Synthesis of Trans-Heteroleptic Carboxylate-Bridged Paddlewheel-type Diruthenium(II,II) Complexes with Poly Aromatic Hydrocarbon Carboxylate

Wataru Kosaka, Taku Kitayama, Tomoka Shimada, Yoshihiro Sekine, and Hitoshi Miyasaka
Chem. Lett., 2025 in press.　

Introduction of substituents for tuning the redox properties of benzoate-bridged paddlewheel diruthenium(II, II) complexes: What does the OH group bring?

Wataru Kosaka, Yudai Watanabe, Taku Kitayama, Chisa Itoh, and Hitoshi Miyasaka
Dalton Trans., 2025, 54, 1838-1849.　DOI: 10.1039/D4DT03020F

Ultrafast Luminescence Detection with Selective Adsorption of Carbon Disulfide in a Gold(I) Metal−Organic Framework

Haruka Yoshino, Masaki Saigo, Takumi Ehara, Kiyoshi Miyata, Ken Onda, Jenny Pirillo, Yuh Hijikata, Shinya Takaishi, Wataru Kosaka, Keni-ichi Otake, Susumu Kitagawa, and Hitoshi Miyasaka
Angew. Chem. Int. Ed., 2025, 64, e202413830 (1-7).　DOI: 10.1002/anie.202413830

Dynamic Spin Reordering in a Hybrid Layered Ferrimagnet with Intercalated Biferrocenium Radicals

Qingxin Liu, Wataru Kosaka, and Hitoshi Miyasaka
Chem. Sci., 2024, 15, 19411-19419.　DOI: 10.1039/D4SC04722B

CO2-actuated spin transition tuning in an interdigitated Hofmann-type coordination polymer

Abhik Paul, Wataru Kosaka, Bhart Kumar, Dibya Jyoti Mondal, Hitoshi Miyasaka and Sanjit Konar
Chem. Sci., 2024, 15, 15610-15616.　DOI: 10.1039/d4sc04266b

Reticular Imine-linked Coordination Polymers Based on Paddlewheel Diruthenium/Dirhodium Nodes: Synthesis and Metal-site Dependent Photocatalytic Reduction of CO2

Chisa Itoh, Masaki Kitada, Mio Kondo, Shigeyuki Masaoka, Haruka Yoshino, Wataru Kosaka, Yusuke Ootani, Junko Matsuda, Momoji Kubo, Toyohiko J. Konno, and Hitoshi Miyasaka
ChemSusChem, 2024, 17, e202400885.　DOI: 10.1002/cssc.202400885

Impact of Layer Stacking Manner on Lithium-Ion-Battery Performance in Electrically Neutral Tetraoxolene-Bridged Iron(II) Hexagonal Layer Metal-Organic Frameworks

Wataru Kosaka, Naoki Eguchi, Taku Kitayama, Ryoma Sato, Ryosuke Nakao, Yoshihiro Sekine, Shinya Hayami, Kouji Taniguchi, and Hitoshi Miyasaka
Chem. Mater., 2024, 36, 3563-3573.　 DOI: 10.1021/acs.chemmater.3c02671

Post-synthetic molecular modifications based on Schiff base condensations for designing functional paddlewheel diruthenium(II, II) complexes

Chisa Itoh, Haruka Yoshino, Taku Kitayama, Wataru Kosaka, and Hitoshi Miyasaka
Dalton Trans., 2024, 53, 444-448.　DOI: 10.1039/d3dt03535b

CO2-Sensitive Porous Magnet: Antiferromagnet Creation from a Paramagnetic Charge-Transfer Layered Metal-Organic Framework

Jun Zhang, Wataru Kosaka, Qingxin Liu, Naoka Amamizu, Yasutaka Kitagawa, and Hitoshi Miyasaka
J. Am. Chem. Soc., 2023, 145, 26179-26189.　DOI: 10.1021/jacs.3c08583

Densely Packed CO2 Aids Charge, Spin, and Lattice Ordering Partially Fluctuated in a Porous Metal-Organic Framework Magnet

Wataru Kosaka, Yoshie Hiwatashi, Naoka Amamizu, Yasutaka Kitagawa, Jun Zhang, and Hitoshi Miyasaka
Angew. Chem. Int. Ed., 2023, 62, e202312205.　DOI: 10.1002/anie.202312205

Guest-induced pore breathing controls the spin state in a cyanido-bridged framework

Michał Magott, Klaudia Płonka, Barbara Sieklucka, Katarzyna Dziedzic-Kocurek, Wataru Kosaka, Hitoshi Miyasaka, and Dawid Pinkowicz
Chem. Sci., 2023, 14, 9651-9663.　DOI: 10.1039/d3sc03255h

Unprecedented highly efficient photoluminescence in a phosphorescent Ag(I) coordination polymer

Haruka Yoshino, Masaki Saigo, Kiyoshi Miyata, Ken Onda, Jenny Pirillo, Yuh Hijikata, Wataru Kosaka, and Hitoshi Miyasaka
Chem. Commun., 2023, 59, 4616-4619. DOI: 10.1039/d3cc00179b

Charge Manipulation in a Series of π-Stacked Pillared-Layer Frameworks by Tuning Electron Donation Ability of Building Blocks

Wataru Kosaka, Taku Kitayama, Chisa Itoh, Hiroki Fukunaga, and Hitoshi Miyasaka
Cryst. Growth Des., 2023, 23, 1238-1246.　Invited for the virtual special issue on “Molecular Magnets and Switchable Magnetic Materials”　DOI: 10.1021/acs.cgd.2c01372

Inter-Layer Magnetic Tuning by Gas Adsorption in π-Stacked Pillared-Layer Framework Magnets

Wataru Kosaka, Honoka Nemoto, Kohei Nagano, Shogo Kawaguchi, Kunihisa Sugimoto, and Hitoshi Miyasaka
Chem. Sci., 2023, 14, 791-800.　DOI: 10.1039/D2SC06337A

Considerations on Gated CO2 Adsorption Behavior in One-Dimensional Porous Coordination Polymers Based on Paddlewheel-Type Dimetal Complexes: What Determines Gate-opening Temperatures?

Wataru Kosaka, Jun Zhang, Yudai Watanabe, and Hitoshi Miyasaka
Inorg. Chem., 2022, 61, 12698-12707.　DOI: 10.1021/acs.inorgchem.2c01734

High stabilization of low valency in a homoleptic ortho-hydroxybenzoate-bridged paddlewheel diruthenium(II,II) complex

Wataru Kosaka, Yudai Watanabe, Chisa Itoh, and Hitoshi Miyasaka
Chem. Lett., 2022, 51, 731-734.　DOI: 10.1246/cl.220195

Crucial Contribution of Polarity for Bulk Photovoltaic Effect in a Series of Non-Centrosymmetric Two-Dimensional Organic-Inorganic Hybrid Perovskites

Po-Jung Huang, Kouji Taniguchi, and Hitoshi Miyasaka
Chem. Mater., 2022, 34, 4428-4436.　DOI: 10.1021/acs.chemmater.2c00094

A Host–Guest Electron Transfer Mechanism for Magnetic and Electronic Modifications in a Redox-Active Metal–Organic Framework

Jun Zhang, Wataru Kosaka, Yasutaka Kitagawa, and Hitoshi Miyasaka
Angew. Chem. Int. Ed., 2022, 61, e202115976 (1-9).　DOI: 10.1002/anie.202115976

Role of intramolecular hydrogen bonding in the redox chemistry of hydroxybenzoate-bridged paddlewheel diruthenium(II, II) complexes

Wataru Kosaka, Yudai Watanabe, Kinanti Hantiyana Aliyah, and Hitoshi Miyasaka
Dalton Trans., 2022, 51, 85-94.　DOI: 10.1039/D1DT03791A

Charge manipulation in metal–organic frameworks: Toward designer functional molecular materials

Hitoshi Miyasaka
Bull. Chem. Soc. Jpn., 2021, 94, 2929-2955.　<Award Account>　DOI: 10.1246/bcsj.20210277

Magnetic Phase Switching Performance in an Fe-Tetraoxolene Layered Metal-Organic Framework via Electrochemical Cycling

Jian Chen, Yoshihiro Sekine, Kouji Taniguchi, and Hitoshi Miyasaka
Inorg. Chem., 2021, 60, 9456-9460.　DOI: 10.1021/acs.inorgchem.1c00576

Magneto-Electric Directional Anisotropy in Polar Soft Ferromagnets of Two-Dimensional Organic-Inorganic Hybrid Perovskites

Kouji Taniguchi, Masaki Nishio, Nobuyuki Abe, Po-jung Huang, Shojiro Kimura, Taka-hisa Arima, and Hitoshi Miyasaka
Angew. Chem. Int. Ed., 2021, 60, 14350-14354.　DOI: 10.1002/anie.202103121

Magnet Creation by Guest Insertion into a Paramagnetic Charge-Flexible Layered Metal-Organic Framework

Jun Zhang, Wataru Kosaka, Hiroyasu Sato, and Hitoshi Miyasaka
J. Am. Chem. Soc., 2021, 143, 7021-7031.　DOI: 10.1021/jacs.1c01537

Chirality-dependent circular photogalvanic effect in enantiomorphic two-dimensional organic–inorganic hybrid perovskites

Po-Jung Huang, Kouji Taniguchi, Masato Shigefuji, Takatsugu Kobayashi, Masakazu Matsubara, Takao Sasagawa, Hiroyasu Sato, and Hitoshi Miyasaka
Adv. Mater., 2021, 33, 2008611 (1-9).　DOI: 10.1002/adma.202008611

Ionicity Diagrams for Electron-Donor and -Acceptor Metal-Organic Frameworks: DA Chains and D2A Layers Obtained from Paddlewheel-Type Diruthenium(II,II) Complexes and Polycyano-Organic Acceptors

Yoshihiro Sekine, Masaki Nishio, Tomoka Shimada, Wataru Kosaka, and Hitoshi Miyasaka
Inorg. Chem., 2021, 60, 3046-3056.　DOI: 10.1021/acs.inorgchem.0c03335

A metal–organic framework that exhibits CO2-induced transitions between paramagnetism and ferrimagnetism

Jun Zhang, Wataru Kosaka, Yasutaka Kitagawa, and Hitoshi Miyasaka
Nature Chem., 2021, 13, 191-199.　DOI: 10.1038/s41557-020-00577-y

Canting Angle Dependence of Single-Chain Magnet Behaviour in Chirality-Introduced Antiferromagnetic Chains of Acetate-Bridged Manganese(III) Salen-Type Complexes

Po-Jung Huang and Hitoshi Miyasaka
Dalton Trans., 2020, 49, 16970-16978.　DOI: 10.1039/D0DT03615C

Fine tuning of intra-lattice electron transfers through site doping in tetraoxolene-bridged iron honeycomb layers

Yoshihiro Sekine, Jian Chen, Naoki Eguchi, and Hitoshi Miyasaka
Chem. Commun., 2020, 56, 10867-10870.　DOI: 10.1039/D0CC03808C

Magnetic Correlation Engineering in Spin-Sandwiched Layered Magnetic Frameworks

Hiroki Fukunaga, Wataru Kosaka, Honoka Nemoto, Kouji Taniguchi, Shogo Kawaguchi, Kunihisa Sugimoto, and Hitoshi Miyasaka
Chem. Eur. J., 2020, 26, 16755-16766. <Hot Paper>　DOI: 10.1002/chem.202002588

CO2-induced spin state switching at room temperature in a monomeric cobalt(II) complex with the porous nature

Manabu Nakaya, Wataru Kosaka, Hitoshi Miyasaka, Yuki Komatsumaru, Shogo Kawaguchi, Kunihisa Sugimoto, Yingjie Zhang, Masaaki Nakamura, Leonard F. Lindoy, and Shinya Hayami
Angew. Chem. Int. Ed., 2020, 59, 10658-10665. <Hot Paper>　DOI: 10.1002/anie.202003811

Chameleonic layered metal-organic frameworks with variable charge-ordered states triggered by temperature and guest molecules

Jian Chen, Yoshihiro Sekine, Atsushi Okazawa, Hiroyasu Sato, Wataru Kosaka, and Hitoshi Miyasaka
Chem. Sci., 2020, 11, 3610-3618.　DOI: 10.1039/D0SC00684J

Electrochemical Development of Magnetic Long-Range Correlations with Tc = 128 K in a Tetraoxolene-Bridged Fe-Based Framework

Jian Chen, Kouji Taniguchi, Yoshihiro Sekine, and Hitoshi Miyasaka
J. Mag. Mag. Mater., 2020, 494, 165818.　DOI: 10.1016/j.jmmm.2019.165818

Bulk Photovoltaic Effect in a Pair of Chiral–Polar Layered Perovskite-Type Lead Iodides Altered by Chirality of Organic Cations

Po-Jung Huang, Kouji Taniguchi, and Hitoshi Miyasaka
J. Am. Chem. Soc., 2019, 141, 14520-14523.　DOI: 10.1021/jacs.9b06815

Control of gas sorption gate-opening in solid solutions of one-dimensional coordination polymers

Jun Zhang, Wataru Kosaka, and Hitoshi Miyasaka
Chem. Lett., 2019, 48, 1308-1311. <Editor's Choice>　DOI: 10.1246/cl.190557

Local-Site Dependency of Magneto-Chiral Dichroism in Enantiopure One-Dimensional Copper(II)-Chromium(III) Coordination Polymers

Kouji Taniguchi, Shuhei Kishiue, Shojiro Kimura, and Hitoshi Miyasaka
J. Phys. Soc. Jpn., 2019, 88, 093708 (1-3).　DOI: 10.7566/JPSJ.88.093708

Strong magnetochiral dichroism for visible light emission in a rationally designed paramagnetic enantiopure molecule

Kouji Taniguchi, Masaki Nishio, Shuhei Kishiue, Po-Jung Huang, Shojiro Kimura, and Hitoshi Miyasaka
Phys. Rev. Mater., 2019, 3, 045202 (1-8).　DOI: 10.1103/PhysRevMaterials.3.045202

Host-Guest Hydrogen Bonding Varies the Charge-State Behavior of Magnetic Sponges

Jun Zhang, Wataru Kosaka, Yasutaka Kitagawa, and Hitoshi Miyasaka
Angew. Chem. Int. Ed., 2019, 58, 7351-7356.　DOI: 10.1002/anie.201902301

In Situ Tracking of Dynamical NO Capture through a Crystal-to-Crystal Transformation from a Gate-Open-Type Chain Porous Coordination Polymer to an NO-Adducted Discrete Isomer

Jun Zhang, Wataru Kosaka, Susumu Kitagawa, Masaki Takata, and Hitoshi Miyasaka
Chem. Eur. J., 2019, 25, 3020-3031.　<VIP>　DOI: 10.1002/chem.201805833

Strong electronic influence of equatorial ligands on frontier orbitals in paddlewheel dichromium(II, II) complexes

Po-Jung Huang, Yoshiki Natori, Yasutaka Kitagawa, Yoshihiro Sekine, Wataru Kosaka, and Hitoshi Miyasaka
Dalton Trans., 2018, 48, 908-914.　DOI: 10.1039/C8DT04347G

Gas-responsive porous magnet distingishes the electron spin of molecular oxygen

Wataru Kosaka, Zhaoyuan Liu, Jun Zhang, Yohei Sato, Akihiro Hori, Ryotaro Matsuda, Sususmu Kitagawa, and Hitoshi Miyasaka
Nat. Commun., 2018, 9, 5420(1-9).　DOI: 10.1038/s41467-018-07889-1

Thermally Induced Valence Tautomeric Transition in a Two-Dimensional Fe-Tetraoxolene Honeycomb Network

Jian Chen, Yoshihiro Sekine, Yuki Komatsumaru, Shinya Hayami, and Hitoshi Miyasaka
Angew. Chem. Int. Ed., 2018, 57, 12043-12047. <VIP>　DOI: 10.1002/anie.201807556

Ionic Donor-Acceptor Chain Derived from an Electron Transfer Reaction of a Paddlewheel-Type Diruthenium(II, II) Complex and N,N’-Dicyanoquinonediimine

Yoshihiro Sekine, Tomoka Shimada, and Hitoshi Miyasaka
Chem. Eur. J., 2018, 24, 13093-13097.　DOI: 10.1002/chem.201802630

Layered Ferrimagnets Constructed from Charge-Transferred Paddlewheel [Ru2] Units and TCNQ Derivatives: The Importance of Interlayer Translational Distance in Determining Magnetic Ground State

Wataru Kosaka, Zhaoyuan Liu, and Hitoshi Miyasaka
Dalton Trans., 2018,47, 11760-11768.　<Themed issue: Frontiers in coordination chemistry and its applications>　DOI: 10.1039/C8DT01566J

Magnetic Sponge Behavior via Electronic State Modulations

Jun Zhang, Wataru Kosaka, Kunihisa Sugimoto, and Hitoshi Miyasaka
J. Am. Chem. Soc., 2018, 140, 5644-5652.　DOI: 10.1021/jacs.8b02428

One-Dimensional Chains of Paddlewheel-Type Dichromium(II,II) Tetraacetate Complexes: Study of Electronic Structure Influenced by σ- and π-Donation of Axial Linkers

Po-Jung Huang, Yoshiki Natori, Yasutaka Kitagawa, Yoshihiro Sekine, Wataru Kosaka, and Hitoshi Miyasaka
Inorg. Chem., 2018, 57, 5371-5379.　DOI: 10.1021/acs.inorgchem.8b00352

Hammett-Law Correlation in the Electron-Donation Ability of trans-HeterolepticBenzoate-Bridged Paddlewheel-Type Diruthenium(II, II) Complexes

Yoshihiro Sekine, Kinanti H. Aliyah, Tomoka Shimada, Jun Zhang, Wataru Kosaka, and Hitoshi Miyasaka
Chem. Lett., 2018, 47, 693-696.　DOI: 10.1246/cl.180155

Charge-Transfer Layered Assembly of a trans-Heteroleptic Paddlewheel-Type Diruthenium(II, II) Complex with a TCNQ Derivative: Electrochemical Tuning of the Magnetism

Kouji Taniguchi, Nanami Shito, Hiroki Fukunaga, and Hitoshi Miyasaka
Chem. Lett., 2018, 47, 664-667.　DOI: 10.1246/cl.180086

Magnetic Switching by the In-Situ Electrochemical Control of Quasi-Spin-Peierls Singlet States in a Three-Dimensional Spin Lattice Incorporating TTF–TCNQ Salts

Hiroki Fukunaga, Masanori Tonouchi, Kouji Taniguchi, Wataru Kosaka, Shojiro Kimura, and Hitoshi Miyasaka
Chem. Eur. J., 2018, 24, 4294-4303.　DOI: 10.1002/chem.201704815

Metamagnetism with TN = 97 K in a layered assembly of paddlewheel [Ru2] units and TCNQ: an empirical rule for interlayer distances determining the magnetic ground state

Wataru Kosaka, Masahisa Itoh, and Hitoshi Miyasaka
Mater. Chem. Frontiers, 2018, 2, 497-504.　<Invited paper for the special issue on π-conjugated system bricolage (figuration) toward functional organic molecular systems>　DOI: 10.1039/C7QM00534B

Magnetic Sponge with Neutral–Ionic Phase Transitions

Wataru Kosaka, Yusuke Takahashi, Masaki Nishio, Keisuke Narushima, Hiroki Fukunaga, and Hitoshi Miyasaka
Adv. Sci.,2018, 5, 1700526 (1-10). <Open Access>　DOI: 10.1002/advs.201700526

Magnetic Phase Switching in a Tetraoxolene-Bridged Honeycomb Ferrimagnet Using a Lithium Ion Battery System

Kouji Taniguchi, Jian Chen, Yoshihiro Sekine, and Hitoshi Miyasaka
Chem. Mater.,2017, 29, 10053-10059.　DOI: 10.1021/acs.chemmater.7b03691

Gate-Open-Type Sorption in a Zigzag Paddlewheel Ru Dimer Chain Compound with a Phenylendiamine Linker Instructed by a Preliminary Structural Change of Desolvation

Changxiao, Dou, Wataru Kosaka, and Hitoshi Miyasaka
Chem. Lett.,2017, 46, 1288-1291.　DOI: 10.1246/cl.170509　<Editor's Choice>

The Effect of Anion-Sublattice Structure on the Displacement Reaction in Copper Sulfides of Rechargeable Magnesium Batteries

Yuta Tashiro, Kouji Taniguchi, and Hitoshi Miyasaka
Chem. Lett.,2017, 46, 1240-1242.　DOI: 10.1246/cl.170503

Magneto-ionic phase control in a quasi-layered donor/acceptor metal–organic framework by means of Li-ion battery system

Kouji Taniguchi, Keisuke Narushima, Kayo Yamagishi, Narumi Shito, Wataru Kosaka, and Hitoshi Miyasaka
JJAP,2017, 56, 060307 (1-4).　DOI: 10.7567/JJAP.56.060307

Built-in TTF-TCNQ charge-transfer salts in π-stacked pillared layer frameworks

Yoshihiro Sekine, Masanori Tonouchi, Taiga Yokoyama, Wataru Kosaka, and Hitoshi Miyasaka
CrystEngComm,2017, 19, 2300-2304.　DOI: 10.1039/C7CE00492C

In Situ Reversible Ionic Control for Non-Volatile Magnetic Phases in a Donor/Acceptor Metal-Organic Framework

Kouji Taniguchi, Keisuke Narushima, Hajime Sagayama, Wataru Kosaka, Nanami Shito, and Hitoshi Miyasaka
Adv. Func. Mater.,2017, 27, 1604990 (1-10).　DOI: 10.1002/adfm.201604990

Stepwise fabrication of donor/acceptor thin films with a charge-transfer molecular wire motif

Yoshihiro Sekine, Taiga Yokoyama, Norihisa Hoshino, Manabu Ishizaki, Katsuhiko Kanaizuka, Tomoyuki Akutagawa, Masa-aki Haga, and Hitoshi Miyasaka
Chem. Commun.,2016, 52, 13983–13986.　DOI: 10.1039/C6CC08310B

Regulation of NO Uptake in Flexible Ru Dimer Chain Compounds with Highly Electron-Donating Dopants

Jun Zhang, Wataru Kosaka, Hiroki Fukunaga, Susumu Kitagawa, Masaki Takata, and Hitoshi Miyasaka
Inorg. Chem.,2016, 55, 12085–12092.　DOI: 10.1021/acs.inorgchem.6b02349

Copper Selenide as a New Cathode Material based on Displacement Reaction for Rechargiable Magnesium Batteries

Yuta Tashiro, Kouji Taniguchi, and Hitoshi Miyasaka
Electrochimica Acta, 2016, 210, 655-661.　DOI: 10.1016/j.electacta.2016.05.202

Trans-heteroleptic carboxylate-bridged paddlewheel diruthenium(II, II) complexes with 2,6-bis(trifluoromethyl)benzoate ligands

Yoshihiro Sekine, Wataru Kosaka, Hirohisa Kano, Changxiao Dou, Taiga Yokoyama, and Hitoshi Miyasaka
Dalton Trans., 2016, 45, 7427-7434.　DOI: 10.1039/C6DT00569A

Construction of an Artificial Ferrimagnetic Lattice by Li-Ion Insertion into a Neutral Donor/Acceptor Metal-Organic Framework

Kouji Taniguchi, Keisuke Narushima, Julien Mahin, Wataru Kosaka, and Hitoshi Miyasaka
Angew. Chem. Int. Ed., 2016, 55, 5238-5242.　DOI: 10.1002/anie.201601672

Tuning of Stepwise Neutral–Ionic Transitions by Acceptor Site-Doping in Alternating Donor/Acceptor Chains

Keita Nakabayashi, Masaki Nishio, and Hitoshi Miyasaka
Inorg. Chem., 2016, 55, 2473–2480.　DOI: 10.1021/acs.inorgchem.5b02858

Electron-Transferred Donor/Acceptor Ferrimagnet with Tc = 91 K in a Layered Assembly of Paddlewheel [Ru2] Units and TCNQ

Wataru Kosaka, Hiroki Fukunaga, and Hitoshi Miyasaka
Inorg. Chem., 2015, 54, 10001-10006.　DOI: 10.1021/acs.inorgchem.5b01776

Crystal-to-crystal transformation of a graphite-like layered compound: a self-locking structure with position-variable intercalated molecules

Masaki Nishio, Natsuko Motokawa, and Hitoshi Miyasaka
CrystEngComm, 2015, 17, 7618-7622.　DOI: 10.1039/C5CE01260K

Charge-disproportionate ordered state with δ = 0.75 in a chemically sensitive donor/acceptor Dδ+2A2δ– layered framework

Hiroki Fukunaga, Takafumi Yoshino, Hajime Sagayama, Jun-ichi Yamaura, Taka-hisa Arima, Wataru Kosaka, and Hitoshi Miyasaka
Chem. Commun., 2015, 51, 7795-7798.　DOI: 10.1039/C5CC01633A

The effect of chlorine and fluorine substitutions on tuning the ionization potential of benzoate-bridged paddlewheel diruthenium(II, II) complexes

Wataru Kosaka, Masahisa Itoh, and Hitoshi Miyasaka
Dalton Trans., 2015, 44, 8156-8168.　DOI: 10.1039/C5DT00505A

Fully Electron-Transferred Donor/Acceptor Layered Frameworks with TCNQ2–

Wataru Kosaka, Takaumi Morita, Taiga Yokoyama, Jun Zhang, and Hitoshi Miyasaka
Inorg. Chem., 2015, 54, 1518–1527.　DOI: 10.1021/ic502513p

Magnet Design via the Integration of Layer and Chain Magnetic Systems in a p-Stacking Pillared Layer Framework

Hiroki Fukunaga and Hitoshi Miyasaka
Angew. Chem. Int. Ed., 2015, 54, 569–573. <VIP>　DOI: 10.1002/anie.201410057

Gate-Opening Gas Adsorption and Host-Guest Interacting Gas Trapping Behavior of Porous Coordination Polymers under Applied AC Electric Fields

Wataru Kosaka, Kayo Yamagishi, Jun Zhang, and Hitoshi Miyasaka
J. Am. Chem. Soc., 2014, 136, 12304–12313.　DOI: 10.1021/ja504992g

Coordination Programming in the Design of Porous Coordination Polymers: Tuning of the Electronic Activity of Frameworks for Selective NO Trapping

Wataru Kosaka, Kayo Yamagishi,Ryotaro Matsuda, Susumu Kitagawa, Masaki Takata, and Hitoshi Miyasaka
Chem. Lett. 2014, 43, 890-892.　DOI: 10.1246/cl.140490

Magnetic Sponge Phenomena Associated with Interchain Dipole–Dipole Interactions in a Series of Ferrimagnetic Chain Compounds Doped with Minor Diamagnetic Species

Masaki Nishio and Hitoshi Miyasaka
Inorg. Chem. 2014, 53, 4716-4723.　DOI: 10.1021/ic500413j

Doping Effect in a Three-Dimensional Donor/Acceptor–Magnet: Percolated Magnetic Pathways Formed Dependent on Local Electron Transfers from Dopant to Acceptor

Hiroki Fukunaga, Wataru Kosaka, and Hitoshi Miyasaka
Chem. Lett., 2014, 43, 541-543.　DOI: 10.1246/cl.131119

Systematic Tuning and Switching of Neutral and Ionic Phases in a Donor/Acceptor Chain Compound by Doping Dummy Donors and Pressure Application

Keita Nakabayashi and Hitoshi Miyasaka
Chem. Eur. J., 2014, 20, 5121-5131.　DOI: 10.1002/chem..201304420

Selective NO Trapping in the Pores of Chain-Type Complex Assemblies Based on Electronically Activated Paddlewheel-Type [Ru2II,II]/[Rh2II,II] Dimers

Wataru Kosaka, Kayo Yamagishi,Akihiro Hori, Hiroshi Sato,Ryotaro Matsuda, Susumu Kitagawa, Masaki Takata, and Hitoshi Miyasaka
J. Am. Chem. Soc., 2013, 135, 18469-18480.　DOI: 10.1021/ja4076056

Carrier Concentration Dependent Conduction in Insulator-Doped Donor/Acceptor Chain Compounds

Masaki Nishio, Norihisa Hoshino, Wataru Kosaka, Tomoyuki Akutagawa, and Hitoshi Miyasaka
J. Am. Chem. Soc., 2013, 135, 17715-17718.　DOI: 10.1021/ja409785a

Modification of charge transfer in a two-dimensional donor/acceptor framework by the insertion of another donor-type molecule into electronegative interlayer pockets

Masaki Nishio, Natsuko Motokawa, Miho Takemura, and Hitoshi Miyasaka
Dalton Trans., 2013, 42, 15898-15901. (Invited to the themed issue on Coordination Programming: Science of Molecular Superstructures towards Chemical Devices)　DOI: 10.1039/C3DT51271A

Axial-Site Modifications of Paddlewheel Diruthenium(II, II) Complexes Supported by Hydrogen Bonding

Wataru Kosaka, Naoto Yamamoto, and Hitoshi Miyasaka
Inorg. Chem., 2013, 52, 9908–9914.　DOI: 10.1021/ic401030r

Polyoxometalate-based frameworks with a linker of paddlewheel diruthenium(II, III) complexes

Akihiro Hashikawa, Yuki Sawada, Yuma Yamamoto, Masaki Nishio, Wataru Kosaka, Yoshihito Hayashi, and Hitoshi Miyasaka
CrystEngComm, 2013, 15, 4852-4859.　DOI: 10.1039/C3CE40426A

Donor/acceptor neutral aggregation of a paddlewheel-type [Ru2II,II] complex and TCNQ

Wataru Kosaka, Yudai Ishii, and Hitoshi Miyasaka
Polyhedron, 2013, 52, 1213-1218. (Invited paper for the Werner special issue of Polyhedron)　DOI: 10.1016/j.poly.2012.06.040

Control of Charge Transfer in Donor/Acceptor Metal–Organic Frameworks

Hitoshi Miyasaka
Acc. Chem. Res., 2013, 46, 248–257.　DOI: 10.1021/ar300102t

CO2 superabsorption in a paddlewheel-type Ru dimer chain compound: Gate-open performance dependent on inter-chain interactions

Wataru Kosaka, Kayo Yamagishi, Hiroki Yoshida, Ryotaro Matsuda, Susumu Kitagawa, Masaki Takata, and Hitoshi Miyasaka
Chem. Commun., 2013, 49, 1594-1596.　DOI:10.1039/C2CC36153A

Observation of two types of magnetization relaxation in a weakly correlated antiferromagnetic chain of MnIII2 single-molecule magnets

Hitoshi Miyasaka, Ayumi Saitoh, and Motohiro Nakano
Dalton Trans., 2012, 41, 13691-13696. (invited to the themed issue: Frontier and Perspectives in Molecule-Based Quantum Magnets)　DOI: 10.1039/C2DT31444D

Honeycomb frameworks with a very large mesh of 39 × 29 Å diameters stabilized by p-stacked coronene molecules

Tomonori Nozaki, Wataru Kosaka, and Hitoshi Miyasaka
CrystEngComm, 2012, 14, 5398-5401.　DOI: 10.1039/C2CE25806D

An ionicity diagram for the family of [{Ru2(CF3CO2)4}2(TCNQRx)] (TCNQRx = R-substituted 7,7,8,8-tetracyanoquinodimethane)

Keita Nakabayashi, Masaki Nishio, Keiko Kubo, Wataru Kosaka, and Hitoshi Miyasaka
Dalton Trans., 2012, 41, 6072-6074.　DOI: 10.1039/C2DT30365E

Coulombic Aggregations of MnIII Salen-Type Complexes and Keggin-Type Polyoxometalates: Isolation of Mn2 Single-Molecule Magnets

Yuki Sawada, Wataru Kosaka, Yoshihito Hayashi, and Hitoshi Miyasaka
Inorg. Chem., 2012, 51, 4824-4832.　DOI: 10.1021/ic300215q
Highlighted in the ACS Virtual Issue:　Quantum Molecular Magnets.

Cyano-Bridged MnIII-MIII Single-Chain Magnets with MIII = CoIII, FeIII, MnIII, and CrIII

Hitoshi Miyasaka, Tomokura Madanbashi, Ayumi Saitoh, Natsuko Motokawa, Ryuta Ishikawa, Masahiro Yamashita, Stefan Bahr, Wolfgang Wernsdorfer, and Rodolphe Clérac
Chem. Eur. J., 2012, 18, 3942-3954.　DOI: 10.1002/chem.201102738

Inorganic Frameworks Made by Combining Paddlewheel Diruthenium(II, III) Complexes and Polyoxometalate Clusters

Yuki Sawada, Yuma Yamamoto, Masaki Nishio, Wataru Kosaka, Yoshihito Hayashi, and Hitoshi Miyasaka
Chem. Lett., 2012, 41, 212-214.　DOI: 10.1246/cl.2012.212

A Dimer-of-Dimers Composed of Paddlewheel Diruthenium(II, III) Complexes and a Bridge of Tetrachlorohydroquinonate(2–) Devived by Intramolecular Charge Transfers

Masahisa Itoh, Yuichiro Asai, Hiromichi Kamo, Akira Miura, and Hitoshi Miyasaka
Chem. Lett., 2012, 41, 26-28.　DOI: 10.1246/cl/2012.26

Isolation of a stable lacunary Dawson-type polyoxomolybdate cluster

Akihiro Hashikawa, Makiko Fujimoto, Yoshihito Hayashi, and Hitoshi Miyasaka
Chem. Commun. 2011, 47, 12361-12363.　DOI: 10.1039/C1CC15439G

Stepwise Neutral-Ionic Phase Transitions in a Covalently-Bonded Donor/Acceptor Chain Compound

Hitoshi Miyasaka, Natsuko Motokawa, Tamiko Chiyo, Miho Takemura, Masahiro Yamashita, Hajime Sagayama, and Taka-hisa Arima
J. Am. Chem. Soc., 2011, 133, 5338-5345.　DOI: 10.1021/ja110007u