CO2-Sensitive Porous Magnet: Antiferromagnet Creation from a Paramagnetic Charge-Transfer Layered Metal-Organic Framework

Jun Zhang, Wataru Kosaka, Qingxin Liu, Naoka Amamizu, Yasutaka Kitagawa,and Hitoshi Miyasaka

J. Am. Chem. Soc. 2023, 145, 26179–26189. DOI: 10.1021/jacs.3c08583

Densely Packed CO2 Aids Charge, Spin, and Lattice Ordering Partially Fluctuated in a Porous Metal-Organic Framework Magnet

Wataru Kosaka, Yoshie Hiwatashi, Naoka Amamizu, Yasutaka Kitagawa, Jun Zhang, and Hitoshi Miyasaka

Angew Chem. Int. Ed. 2023, 62, e202312205. <Open Access> <Hot Paper> DOI: 10.1002/anie.202312205

Appearance of a photoinduced hidden state in the electron donor–acceptor type metal–organic framework (NPr4)2[Fe2(Cl2An)3]

Samiran Banu, Mone Kato, Kou Takubo, Yoichi Okimoto, Shinya Koshihara, Kaoru Iwano, Wataru Kosaka, Hitoshi Miyasaka, and Tadahiko Ishikawa

Adv. Optical Mater.2023, 2301554. <Open Access> DOI: 10.1002/adom.202301554

Guest-Induced Pore Breathing Controls Spin State in a Cyanido-Bridged Framework

Michał Magott, Klaudia Płonka, Barbara Sieklucka, Katarzyna Dziedzic-Kocurek, Wataru Kosaka, Hitoshi Miyasaka, Dawid Pinkowicz

Chem. Sci. 2023, 14, 9651–9663. <Cover artwork> DOI: 10.1039/d3sc03255h

Unprecedented highly efficient photoluminescence in a phosphorescent Ag(I) coordination polymer

Haruka Yoshino, Masaki Saigo, Kiyoshi Miyata, Ken Onda, Jenny Pirillo, Yuh Hijikata, Wataru Kosaka, and Hitoshi Miyasaka

Chem. Commun. 2023, 59, 4616-4619. DOI: 10.1039/d3cc00179b

The Introduction of a Base Component to Porous Organic Salts and Their CO2 Storage Capability

Takahiro Ami, Kouki Oka, Keiho Tsuchiya, Wataru Kosaka, Hitoshi Miyasaka, and Norimitsu Tohnai

CrystEngComm 2023, 25, 2321-2325. DOI: 10.1039/d3ce00086a

Charge Manipulation in a Series of p-Stacked Pillared-Layer Frameworks by Tuning Electron Donation Ability of Building Blocks

Wataru Kosaka, Taku Kitayama, Chisa Itoh, Hiroki Fukunaga, and Hitoshi Miyasaka

Cryst. Growth Des. 2023, 23, 1238-1246. The Virtual Special issue on Molecular Magnets and Switchable Magnetic Materials. <Cover artwork> DOI: 10.1021/acs.cgd.2c01372

Inter-Layer Magnetic Tuning by Gas Adsorption in p-Stacked Pillared-Layer Framework Magnets

Wataru Kosaka, Honoka Nemoto, Kohei Nagano, Shogo Kawaguchi, Kunihisa Sugimoto, and Hitoshi Miyasaka

Chem. Sci. 2023, 14, 791–800. <Outside cover artwork> DOI: 10.1039/D2SC06337A

Chiral weak ferromagnets formed in one-dimensional organic-inorganic hybrid manganese chloride hydrates

Kouji Taniguchi, Po-Jung Huang, Shojiro Kimura, and Hitoshi Miyasaka

Dalton Trans., 2022, 51, 17030-17034. DOI: 10.1039/s2dt02928f

Considerations on Gated CO2 Adsorption Behavior in One-Dimensional Porous Coordination Polymers Based on Paddlewheel-Type Dimetal Complexes: What Determines Gate-Opening Temperatures?

Wataru Kosaka, Jun Zhang, Yudai Watanabe, and Hitoshi Miyasaka

Inorg. Chem., 2022, 61, 12698-12707. DOI: 10.1021/acs.inorgchem.2c01734

High stabilization of low valency in a homoleptic ortho-hydroxybenzoate-bridged paddlewheel diruthenium(II,II) complex

Wataru Kosaka, Yudai Watanabe, Chisa Itoh, and Hitoshi Miyasaka

Chem. Lett., 2022, 51, 731-734. DOI: 10.1246/cl.220195

Syntheses, Structures, and Properties of Coordination Polymers with 2,5-Dihydroxy-1,4-Benzoquinone and 4,4’-Bipyridyl Synthesized by In Situ Hydrolysis Method

Daiki Yamazui, Kaiji Uchida, Shohei Koyama, Bin Wu, Hiroaki Iguchi,Wataru Kosaka, Hitoshi Miyasaka, and Shinya Takaishi

ACS Omega, 2022, 7, 18259-18266. DOI: 10.1021/acsomega.1c07077

Crucial Contribution of Polarity for Bulk Photovoltaic Effect in a Series of Non-Centrosymmetric Two-Dimensional Organic-Inorganic Hybrid Perovskites

Po-Jung Huang, Kouji Taniguchi, and Hitoshi Miyasaka

Chem. Mater., 2022, 34, 4428-4436. DOI: 10.1021/acs.chemmater.2c00094

A Host–Guest Electron Transfer Mechanism for Magnetic and Electronic Modifications in a Redox-Active Metal–Organic Framework

Jun Zhang, Wataru Kosaka, Yasutaka Kitagawa, and Hitoshi Miyasaka

Angew. Chem. Int. Ed., 2022, 61, e202115976 (1-9). <Back cover artwork> DOI: 10.1002/anie.202115976

Role of intramolecular hydrogen bonding in the redox chemistry of hydroxybenzoate-bridged paddlewheel diruthenium(II, II) complexes

Wataru Kosaka, Yudai Watanabe, Kinanti Hantiyana Aliyah and Hitoshi Miyasaka

Dalton Trans., 2022, 51, 85-94. DOI: 10.1039/d1dt03791a

Charge manipulation in metal–organic frameworks: Toward designer functional molecular materials

Hitoshi Miyasaka

Bull. Chem. Soc. Jpn. 2021, 94, 2929-2955. DOI: 10.1246/bcsj.20210277 <Award Account; Masterpiece Materials with Functional Excellence>

Tunable Synchronicity of Molecular Valence Tautomerism with Macroscopic Solid-liquid Transition by Molecular Lattice Engineering

Mayumi Chida, Satoru Takahashi, Ryunosuke Konishi, Takeshi Matsumoto, Akinobu Nakada, Masanori Wakizaka, Wataru Kosaka,Hitoshi Miyasaka,and Ho-Chol Chang*

Chem. Eur. J., 2021, 27, 16354-16366. DOI: 10.1002/chem.202103090 <Back Cover>

Magnetic Phase Switching Performance in an Fe-Tetraoxolene Layered Metal-Organic Framework via Electrochemical Cycling

Jian Chen, Kouji Taniguchi, Yoshihiro Sekine, Hitoshi Miyasaka

Inorg. Chem.,2021, 60, 9456-9460. DOI: 10.1021/acs.inorgchem.1c00576

Guest-Selective and Reversible Magnetic Phase Switching in a Pseudo-Pillared-Layer Porous Magnet

Haruka Yoshino, Narumi Tomokage, Akio Mishima, Benjamin Le Ouay, Ryo Ohtani, Wataru Kosaka, Hitoshi Miyasaka, and Masaaki Ohba*

Chem. Commun., 2021, 57, 5211-5214. DOI: 10.1039/d1cc01526e

Magneto-Electric Coupling in Polar Soft Ferromagnets of Two-Dimensional Organic-Inorganic Hybrid Perovskites

Kouji Taniguchi,* Masaki Nishio, Nobuyuki Abe, Po-Jung Huang, Shojiro Kumura Taka-hisa Arima, and Hitoshi Miyasaka

Angew. Chem. Int. Ed., 2021, 60, 14350-14354. DOI: 10.1002/anie.202103121

Magnet Creation by Guest Insertion into a Paramagnetic Charge-Flexible Layered Metal-Organic Framework

Jun Zhang, Wataru Kosaka, Hiroyasu Sato, and Hitoshi Miyasaka

J. Am. Chem. Soc., 2021, 143, 7021-7031. <Supprementaly Cover Artwork> DOI: 10.1021/jacs.1c01537

Chirality-dependent circular photogalvanic effect in enantiomorphic two-dimensional organic–inorganic hybrid perovskites

Po-Jung Huang, Kouji Taniguchi, Masato Shigefuji, Takatsugu Kobayashi, Masakazu Matsubara, Takao Sasagawa, Hiroyasu Sato, and Hitoshi Miyasaka

Adv. Mater., 2021, 33, 2008611 (1-9). DOI: 10.1002/adma.202008611

Ionicity Diagrams for Electron-Donor and -Acceptor Metal-Organic Frameworks: DA Chains and D2A Layers Obtained from Paddlewheel-Type Diruthenium(II,II) Complexes and Polycyano-Organic Acceptors

Yoshihiro Sekine, Masaki Nishio, Tomoka Shimada, Wataru Kosaka, Hitoshi Miyasaka

Inorg. Chem., 2021, 60, 3046-3056. <Supprementaly Cover Artwork> DOI: 10.1021/acs.inorgchem.0c03335

A metal–organic framework that exhibits CO2-induced transitions between paramagnetism and ferrimagnetism

Jun Zhang, Wataru Kosaka, Yasutaka Kitagawa, Hitoshi Miyasaka

Nature Chem., 2021, 13, 191-199. DOI: 10.1038/s41557-020-00577-y

Magnetic Correlation Engineering in Spin-Sandwiched Layered Magnets

Hiroki Fukunaga, Wataru Kosaka, Honoka Nemoto, Kouji Taniguchi, Shingo Kawaguchi, Kunihisa Sugimoto, and Hitoshi Miyasaka

Chem. Eur. J., 2020, 26, 16755-16766. <Hot Paper> DOI: 10.1002/chem.202002588

Canting Angle Dependence of Single-Chain Magnet Behaviour in Chirality-Introduced Antiferromagnetic Chains of Acetate-Bridged Manganese(III) Salen-Type Complexes

Po-Jung Huang and Hitoshi Miyasaka

Dalton Trans., 2020, 49, 16970–16978. DOI: 10.1039/d0dt03615c

Spin-Ice-Like Magnetic Relaxation of a Two-Dimensional Network based on Mn(III) Salen-Type Single-Molecule Magnet

Chihiro Kachi-Terajima, Tasuku Eiba, Rikako Ishii, Hitoshi Miyasaka, Yuta Kodama, and Toshiaki Saito

Angew. Chem. Int. Ed. 2020, 59, 22048-22053. <Hot Paper> DOI: 10.1002/anie.202008914

Coordination Distortion Induced Water Adsorption in Hydrophobic Flexible Metal–Organic Frameworks

Yoshinobu Kamakura, Arata Hikawa, Hirofumi Yoshikawa, Wataru Kosaka, Hitoshi Miyasaka, and Daisuke Tanaka

Chem. Commun., 2020, 56, 9106-9109. DOI: 10.1039/d0cc03772a

Fine tuning of intra-lattice electron transfers through site doping in tetraoxolene-bridged iron honeycomb layers

Yoshihiro Sekine, Jian Chen, Naoki Eguchi, and Hitoshi Miyasaka

Chem. Commun., 2020, 56, 10867-10870. DOI: 10.1039/d0cc03808c

CO2-induced spin state switching at room temperature in a monomeric cobalt(II) complex with the porous nature

Manabu Nakaya, Wataru Kosaka, Hitoshi Miyasaka, Yuki Komatsumaru, Shogo Kawaguchi, Kunihisa Sugimoto, Yingjie Zhang, Masaaki Nakamura, Leonard F. Lindoy and Shinya Hayami

Angew. Chem. Int. Ed., 2020, 59, 10658-10665. <Hot paper> DOI: 10.1002/anie.202003811

Chameleonic layered metal-organic frameworks with variable charge-ordered states triggered by temperature and guest molecules

Jian Chen, Yoshihiro Sekine,Atsushi Okazawa, Hiroyasu Sato, Wataru Kosaka,and Hitoshi Miyasaka

Chem. Sci., 2020, 11, 3610–3618. DOI: 10.1039/D0SC00684J

Electrochemical Development of Magnetic Long-Range Correlations with Tc = 128 K in a Tetraoxolene-Bridged Fe-Based Framework

Jian Chen, Kouji Taniguchi, Yoshihiro Sekine, and Hitoshi Miyasaka

J. Mag. Mag. Mater., 2020, 494, 165818. A special issue for ICMM2018. DOI: 10. 1016/j.jmmm.2019.165818

錯体化学会フロンティア選書　フロンティア　機能高分子金属錯体（西原寛　山元公寿編著）

４章　光電磁機能　4.5　一次元磁性鎖

宮坂　等

三共出版, 2020, 423-444. ISBN 978-4-7827-0791-3

クリーンエネルギー2020「キラルペロブスカイト系半導体での光電変換ヘテロ界面を用いない単一物質による光電変換材料の開発」

谷口耕治, 黃柏融, 宮坂等

日本工業出版, 2020, Vol. 29 No 2 P31.　

Bulk Photovoltaic Effect in a Pair of Chiral–Polar Layered Perovskite–Type Lead Iodides Altered by Chirality of Organic Cations

Po-Jung Huang, Kouji Taniguchi, Hitoshi Miyasaka

J. Am. Chem. Soc., 2019, 141, 14520-14523. DOI: 10.1021/jacs.9b06815

Control of gas sorption gate-opening in solid solutions of one-dimensional coordination polymers

Jun Zhang, Wataru Kosaka, and Hitoshi Miyasaka

Chem. Lett., 2019, 48, 1308-1311. Editor’s Choice DOI: 10.1246/cl.190557

Water-vapor sensitive spin-state switching in an iron(III) complex with nucleobase pendants making flexible hydrogen-bonded frameworks

Koichi Kagesawa, Yuki Ichikawa, Hiroaki Iguchi, Brian K. Breedlove, Zhaoyang Li, Masahiro Yamashita, Atsushi Okazawa, Wataru Kosaka, and Hitoshi Miyasaka

Chem. Lett., 2019, 48, 1221-1224. Editor’s Choice DOI: 10. 1246/cl.190532

Local-Site Dependency of Magneto-Chiral Dichroism in Enantiopure One-Dimensional Copper(II)-Chromium(III) Coordination Polymers

Kouji Taniguchi, Shuhei Kishiue, Shojiro Kimura, and Hitoshi Miyasaka

J. Phys. Soc. Jpn., 2019, 88, 093708(1-3). DOI: 10.7566/JPSJ.88.093708

Strong magnetochiral dichroism for visible light emission in a rationally designed paramagnetic enantiopure molecule

Kouji Taniguchi, Masahiro Nishio, Shuhei Kishiue, Po-Jung Hang, Shojiro Kimura, Hitoshi Miyasaka

Phys. Rev. Mater., 2019, 3, 045202 (1–8). DOI: 10.1103/PhysRevMaterials.3.045202

Host–Guest Hydrogen Bonding Varies the Charge-State Behavior of Magnetic Sponges

Jun Zhang, Wataru Kosaka, Yasutaka Kitagawa, and Hitoshi Miyasaka

Angew. Chem. Int. Ed., 2019, 58, 7351–7356. DOI: 10.1002/anie.201902301

In Situ Tracking of Dynamical NO Capture through a Crystal-to-Crystal Transformation from a Gate-Open-Type Chain Porous Coordination Polymer to an NO-Adducted Discrete Isomer

Jun Zhang, Wataru Kosaka, Susumu Kitagawa, Masaki Takata, and Hitoshi Miyasaka

Chem. Eur. J., 2019, 25, 3020-3031. Very Inportnat Paper (VIP) DOI: 10.1002/chem.201805833

Hybrid Materials Composed of Organic Radicals and Ru Dimers

Hitoshi Miyasaka

World Scientific Reference on Spin in Organics: Volume 4 -Spin in Organics, Materials and Energy Vol. 10,Editors: Zeev Valy Vardeny and Markus Wohlgenannt; Volume Editor: Joel S. Miller

Chapter 4,p169-205. World Scientific Pub. Co. Pte. Ltd. ISBN 978-981-3229-07-5 (Vol 4), 2018.

Strong electronic influence of equatorial ligands on frontier orbitals in paddlewheel dichromium(II, II) complexes

Po-Jung Huang, Yoshiki Natori, Yasutaka Kitagawa, Yoshihiro Sekine, Wataru Kosaka and Hitoshi Miyasaka

Dalton Trans., 2018, 48, 908-914. DOI: 10.1039/C8DT04347G

Porous magnet responsive to spins of oxygen molecules

Wataru Kosaka, Zhaoyuan Liu, Jun Zhang, Yohei Sato, Akihiro Hori, Ryotaro Matsuda, Susumu Kitagawa, Hitoshi Miyasaka

Nat. Commun., 2018, 9, 5420(1-9). DOI: 10.1038/s41467-018-07889-1

Development of ferromagnetic fluctuations in heavily overdoped Bi-2201 copper oxides

Koshi Kurashima, Tadashi Adachi, Kensuke M. Suzuki, Yasushi Fukunaga, Takayuki Kawamata, Takayuki Noji, Hitoshi Miyasaka, Isao Watanabe, Masanori Miyazaki, Akihiro Koda, Yoji Koike

Phys. Rev. Lett., 2018, 121, 057002 (1-6). DOI: 10.1103/PhysRevLett.121.057002

Thermally Induced Valence Tautomeric Transition in a Two-Dimensional Fe-Tetraoxolene Honeycomb Network

Jian Chen, Yoshihiro Sekine, Yuki Komatsumaru, Shinya Hayami, and Hitoshi Miyasaka

Angew. Chem. Int. Ed., 2018, 57, 12043–12047. Very Important Paper <VIP> DOI: 10.1002/anie.201807556

Ionic Donor-Acceptor Chain Derived from an Electron Transfer Reaction of a Paddlewheel-Type Diruthenium(II, II) Complex and N,N’-Dicyanoquinonediimine

Yoshihiro Sekine, Tomoka Shimada, and Hitoshi Miyasaka

Chem. Eur. J., 2018, 24, 13093–13097. DOI: 10.1002/chem.201802630

Layered Ferrimagnets Constructed from Charge-Transferred Paddlewheel [Ru2] Units and TCNQ Derivatives: The Importance of Interlayer Translational Distance in Determining Magnetic Ground State

Wataru Kosaka, Zhaoyuan Liu, and Hitoshi Miyasaka

Dalton Trans., 2018, 47, 11760–11768. Themed issue invitation: Frontiers in coordination chemistry and its applications DOI: 10.1039/C8DT01566J

One-Dimensional Chains of Paddlewheel-Type Dichromium(II,II) Tetraacetate Complexes: Study of Electronic Structure Influenced by σ- and π-Donation of Axial Linkers

Po-Jung Huang, Yoshiki Natori, Yasutaka Kitagawa, Yoshihiro Sekine, Wataru Kosaka, and Hitoshi Miyasaka

Inorg. Chem., 2018 57, 5371-5379. DOI: 10.1021/acs.inorgchem.8b00352

Magnetic Sponge Behavior via Electronic State Modulations

Jun Zhang, Wataru Kosaka, Kunihisa Sugimoto, and Hitoshi Miyasaka

J. Am. Chem. Soc., 2018, 140, 5644-5652. DOI: 10.1021/jacs.8b02428

Hammett-Law Correlation in the Electron-Donation Ability of trans-Heteroleptic Benzoate-Bridged Paddlewheel-Type Diruthenium(II, II) Complexes

Yoshihiro Sekine, Kinanti H. Aliyah, Tomoka Shimada, Jun Zhang, Wataru Kosaka, and Hitoshi Miyasaka

Chem. Lett., 2018, 47, 693-696. DOI: 10.1246/cl.180155

Charge-Transfer Layered Assembly of a trans-Heteroleptic Paddlewheel-Type Diruthenium (II, II) Complex with a TCNQ Derivative: Electrochemical Tuning of the Magnetism

Kouji Taniguchi, Nanami Shito, Hiroki Fukunaga, and Hitoshi Miyasaka

Chem. Lett., 2018, 47, 664–667. DOI: 10.1246/cl.180086

Magnetic Switching by the In-Situ Electrochemical Control of Quasi-Spin-Peierls Singlet States in a Three-Dimensional Spin Lattice Incorporating TTF–TCNQ Salts

Hiroki Fukunaga, Masanori Tonouchi, Kouji Taniguchi, Wataru Kosaka, Shojiro Kimura, and Hitoshi Miyasaka

Chem. Eur. J., 2018, 24, 4294–4303. DOI: 10.1002/chem.201704815

Metamagnetism with TN = 97 K in a Layered Assembly of Paddlewheel [Ru2] Units and TCNQ: An Empirical Rule for Interlayer Distances Determining the Magnetic Ground State

Wataru Kosaka, Masahisa Itoh, and Hitoshi Miyasaka

Mater. Chem. Frontiers, 2018, 2, 497–504. Themed issue for p-conjugated molecular materials (Invited paper)

Magnetic Sponge with Neutral–Ionic Phasse Transitions

Wataru Kosaka, Yusuke Takahashi, Masaki Nishio, Keisuke Narushima, Hiroki Fukunaga, and Hitoshi Miyasaka

Adv. Sci., 2018, 5, 1700526 (1-10). DOI: 10.1002/advs.201700526

Gate-Open-Type Sorption in a Zigzag Paddlewheel Ru dimer Chain Compound with a Phenylendiamine Linker Instructed by a Preliminary Structural Change of Desolvation

Changxiao, Dou, Wataru Kosaka, Hitoshi Miyasaka

Chem. Lett., 2017, 46, 1288–1291. DOI: 10.1246/cl.170509 Selected as Editor’s Choice

The Effect of Anion-Sublattice Structure on the Displacement Reaction in Copper Sulfide Cathodes of Rechargeable Magnesium Batteries

Yuta Tashiro, Kouji Taniguchi, Hitoshi Miyasaka

Chem. Lett., 2017, 46, 1240–1242. DOI: 10.1246/cl.170503

Syntheses, structures and magnetic properties of tetranuclear cubane-type and heptanuclear wheel-type nickel(II) complexes with 3-methoxysalicylic acid derivatives

Fumiya Kobayashi, Ryo Ohtani, Saki Teraoka, Wataru Kosaka, Hitoshi Miyasaka, Yingjie Zhang, Leonard F. Lindoy, Shinya Hayami, Masaaki Nakamura

Dalton Trans., 2017, 46, 8555–8561. DOI: 10.1039/c7dt01757j

Three Dimensional Porous Hofmann Clathrate [MIIPtII(CN)4]∞ (M = Co, Ni) Synthesized by Using Postsynthetic Reductive Elimination

Takuro Okamura, Bin Wu, Hiroaki Iguchi, Brian K. Breedlove, Masahiro Yamashita, Wataru Kosaka, Hitoshi Miyasaka, Shinya Takaishi

Chem. Commun., 2017, 53, 6512–6515. DOI: 10.1039/C7CC01766A

Ferromagnetic Exchange Coupling in a Family of MnIII Salen-Type Schiff-Base Out-of-Plane Dimers

Chihiro Kachi-Terajima, Rikako Ishii, Yoshiaki Tojo, Masato Fukuda, Yasutaka Kitagawa, Mizuki Asaoka, Hitoshi Miyasaka

J. Phys. Chem. C, 2017, 121, 12454–12468. DOI: 10.1021/acs.jpcc.7b03336

Magneto-ionic phase control in a quasi-layered donor/acceptor metal–organic framework by means of a Li-ion battery system

Kouji Taniguchi, Keisuke Narushima, Kayo Yamagishi, Nanami Shito, Wataru Kosaka, and Hitoshi Miyasaka

Japanese Journal of Applied Physics (JJAP), 2017, 56, 060307 (1–4). DOI: 10.7567/JJAP.56.060307

Built-in TTF-TCNQ charge-transfer salts in p-stacked pillared layer frameworks

Yoshihiro Sekine, Masanori Tonouchi, Taiga Yokoyama, Wataru Kosaka, and Hitoshi Miyasaka

CrystEngComm, 2017, 19, 2300–2304. DOI: 10.1039/C7CE00492C

Slow Relaxation of the Magnetization Observed in an Antiferromagnetically Ordered Phase for SCM-Based Two-Dimensional Layered Compounds

Koichi Kagesawa, Yuki Nishimura, Hiroki Yoshida, Brian K. Breedlove, Masahiro Yamashita, and Hitoshi Miyasaka

Dalton Trans. 2017, 46, 3170–3178. DOI: 10.1039/C6DT04636C

In Situ Reversible Ionic Control for Non-Volatile Magnetic Phases in a Donor/Acceptor Metal-Organic Framework

Kouji Taniguchi, Keisuke Narushima, Hajime Sagayama, Wataru Kosaka, Nanami Shito, and Hitoshi Miyasaka

Adv. Func. Mater. 2017, 27, 1604990 (1-10). DOI: 10.1002/adfm.201604990

Molecular Magnetic Materials: Concepts and Applications (Barbara Sieklucka, Dawid Pinkowicz edited.)

Chapter 15, Conductive Molecular Magnets

Yoshihiro Sekine, Wataru Kosaka, Kouji Taniguchi, and Hitoshi Miyasaka,2016, p369-404, Wiley-VCH

Stepwise fabrication of donor/acceptor thin films with a charge-transfer molecular wire motif

Yoshihiro Sekine, Taiga Yokoyama, Norihisa Hoshino, Manabu Ishizaki, Katsuhiko Kanaizuka, Tomoyuki Akutagawa, Masa-aki Haga, and Hitoshi Miyasaka

Chem. Commun.2016,52, 13983-13986. DOI: 10.1039/C6CC08310B

Regulation of NO Uptake in Flexible Ru Dimer Chain Compounds with Highly Electron-Donating Dopants

Jun Zhang, Wataru Kosaka, Hiroki Fukunaga, Susumu Kitagawa, Masaki Takata, and Hitoshi Miyasaka

Inrog. Chem.2016,55, 12085-12092. DOI: 10.1021/acs.inorgchem.6b02349

Copper Selenide as a New Cathode Material based on Displacement Reaction for Rechargeable Magnesium Batteries

Yuta Tashiro, Kouji Taniguchi, and Hitoshi Miyasaka

Electrochimica Acta 2016, 210, 655-661. DOI: 10.1016/j.electacta.2016.05.202

Trans-heteroleptic carboxylate-bridged paddlewheel diruthenium(II, II) complexes with 2,6-bis(trifluoromethyl)benzoate ligands

Yoshihiro Sekine, Wataru Kosaka, Hirohisa Kano, Changxiao Dou, Taiga Yokoyama, and Hitoshi Miyasaka

Dalton Trans. 2016, 45, 7427-7434. DOI: 10.1039/C6DT00569A

Construction of an Artificial Ferrimagnetic Lattice by Li-Ion Insertion into a Neutral Donor/Acceptor Metal-Organic Framework

Kouji Taniguchi, Keisuke Narushima, Julien Mahin, Wataru Kosaka, and Hitoshi Miyasaka

Angew. Chem. Int. Ed., 2016, 55, 5238-5242. DOI: 10.1002/anie.201601672 and DOI: 10.1002/ange.201601672

Tuning of Stepwise Neutral–Ionic Transitions by Acceptor Site-Doping in Alternating Donor/Acceptor Chains

Keita Nakabayashi, Masaki Nishio, Hitoshi Miyasaka

Inorg. Chem.,2016, 55, 2473–2480. DOI: 10.1021/acs.inorgchem.5b02858

ナノ空間材料ハンドブック　ナノ多孔性材料、ナノ層状物質等が切り開く新たな応用展開（有賀克彦監修） 第２章　金属錯体系（MOF類）４節　酸化還元活性MOF　—選択的ガス吸着と物性制御—

高坂　亘、宮坂　等

エヌ・ティー・エス（NTS）, 2016, 164–175.

Electron-Transferred Donor/Acceptor Ferrimagnet with Tc = 91 K in a Layered Assembly of Paddlewheel [Ru2] Units and TCNQ

Wataru Kosaka, Hiroki Fukunaga, and Hitoshi Miyasaka

Inorg. Chem., 2015, 54, 10001-10006. DOI: 10.1021/acs.inorgchem.5b01776

Crystal-to-crystal transformation of a graphite-like layered compound: a self-locking structure with position-variable intercalated molecules

Masaki Nishio, Natsuko Motokawa, and Hitoshi Miyasaka

CrystEngComm, 2015, 17, 7618-7622. DOI: 10.1039/C5CE01260K

解説　分子パーツを組み上げて三次元磁性体を創る―新しい“ピラードレイヤー構造”というアプローチ

化学, 化学同人, 2015, 70 (5月号), 27-32.　表紙採用

Charge-disproportionate ordered state with δ = 0.75 in a chemically sensitive donor/acceptor Dδ+2A2δ– layered framework

Hiroki Fukunaga, Takafumi Yoshino, Hajime Sagayama, Jun-ichi Yamaura, Taka-hisa Arima, Wataru Kosaka, and Hitoshi Miyasaka

Chem. Commun., 2015, 51, 7795-7798. DOI: 10.1039/C5CC01633A

The effect of chlorine and fluorine substitutions on tuning the ionization potential of benzoate-bridged paddlewheel diruthenium(II, II) complexes

Wataru Kosaka, Masahisa Itoh, and Hitoshi Miyasaka

Dalton Trans., 2015, 44, 8156-8168. DOI: 10.1039/C5DT00505A

Fully Electron-Transferred Donor/Acceptor Layered Frameworks with TCNQ2–

Wataru Kosaka, Takaumi Morita, Taiga Yokoyama, Jun Zhang, and Hitoshi Miyasaka

Inorg. Chem., 2015, 54, 1518–1527. DOI: 10.1021/ic502513p

Magnet Design via the Integration of Layer and Chain Magnetic Systems in a π-Stacking Pillared Layer Framework

Hiroki Fukunaga and Hitoshi Miyasaka

Angew. Chem. Int. Ed., 2015, 54, 569–573. Very Important Paper (VIP) DOI: 10.1002/anie.201410057

CSJカレントレビュー16　スピン化学が拓く分子磁性の新展開: 設計から機能化まで（日本化学会編集）

フロントランナーに聞く（座談会）　分子磁性研究の新しい潮流の方向性

Chapter 11　金属錯体一次元磁性鎖：ナノワイヤーから相転移化合物まで

宮坂　等

化学同人, 2014, 2–11, 124–131.

Gate-Opening Gas Adsorption and Host-Guest Interacting Gas Trapping Behavior of Porous Coordination Polymers under Applied AC Electric Fields

Wataru Kosaka, Kayo Yamagishi, Jun Zhang, Hitoshi Miyasaka

J. Am. Chem. Soc., 2014, 136, 12304–12313. DOI: 10.1021/ja504992g

Doping Effect in a Three-Dimensional Donor/Acceptor–Magnet: Percolated Magnetic Pathways Formed Dependent on Local Electron Transfers from Dopant to Acceptor

Hiroki Fukunaga, Wataru Kosaka, Hitoshi Miyasaka

Chem. Lett., 2014, 43, 541-543. DOI: 10.1246/cl.131119

Magnetic Sponge Phenomena Associated with Interchain Dipole–Dipole Interactions in a Series of Ferrimagnetic Chain Compounds Doped with Minor Diamagnetic Species

Masaki Nishio, and Hitoshi Miyasaka

Inorg. Chem., 2014, 53, 4716-4723. DOI: 10.1021/ic500413j

Coordination Programming in the Design of Porous Coordination Polymers: Tuning of the Electronic Activity of Frameworks for Selective NO Trapping

Wataru Kosaka, Kayo Yamagishi, Ryotaro Matsuda, Susumu Kitagawa, Masaki Takata, and Hitoshi Miyasaka

Chem. Lett., 2014, 43, 890-892. DOI: 10.1246/cl.140490

Systematic Tuning and Switching of Neutral and Ionic Phases in a Donor/Acceptor Chain Compound by Doping Dummy Donors and Pressure Application

Keita Nakabayashi, and Hitoshi Miyasaka

Chem. Eur. J., 2014, 20, 5121-5131. DOI: 10.1002/chem..2013044202013

Selective NO Trapping in the Pores of Chain-Type Complex Assemblies Based on Electronically Activated Paddlewheel-Type [Ru2II,II]/[Rh2II,II] Dimers

Wataru Kosaka, Kayo Yamagishi, Akihiro Hori, Hiroshi Sato, Ryotaro Matsuda, Susumu Kitagawa, Masaki Takata, and Hitoshi Miyasaka

J. Am. Chem. Soc., 2013, 135, 18469-18480. DOI: 10.1021/ja4076056

Carrier Concentration Dependent Conduction in Insulator-Doped Donor/Acceptor Chain Compounds

Masaki Nishio, Norihisa Hoshino, Wataru Kosaka, Tomoyuki Akutagawa, and Hitoshi Miyasaka

J. Am. Chem. Soc., 2013, 135, 17715-17718. DOI: 10.1021/ja409785a

Modification of charge transfer in a two-dimensional donor/acceptor framework by the insertion of another donor-type molecule into electronegative interlayer pockets

Masaki Nishio, Natsuko Motokawa, Miho Takemura, Hitoshi Miyasaka

Dalton Trans., 2013, 42, 15898-15901. (Invited to the themed issue on Coordination Programming: Science of Molecular Superstructures towards Chemical Devices) DOI: 10.1039/C3DT51271A

Axial-Site Modifications of Paddlewheel Diruthenium(II, II) Complexes Supported by Hydrogen Bonding

Wataru Kosaka, Naoto Yamamoto, Hitoshi Miyasaka

Inorg. Chem., 2013, 52, 9908–9914. DOI: 10.1021/ic401030r

Polyoxometalate-based frameworks with a linker of paddlewheel diruthenium(II, III) complexes

Akihiro Hashikawa, Yuki Sawada, Yuma Yamamoto, Masaki Nishio, Wataru Kosaka, Yoshihito Hayashi and Hitoshi Miyasaka

CrystEngComm, 2013, 15, 4852-4859. DOI: 10.1039/C3CE40426A

Control of Charge-Transfer in Donor/Acceptor Metal–Organic Frameworks

Hitoshi Miyasaka

Acc. Chem. Res., 2013, 46, 248-257.. DOI: 10.1021/ar300102t

Donor/acceptor neutral aggregation of a paddlewheel-type [Ru2II,II] complex and TCNQ

Wataru Kosaka, Yudai Ishii, Hitoshi Miyasaka

Polyhedron, 2013, 52, 1213-1218. DOI: 10.1016/j.poly.2012.06.040 (invited paper for the Werner special issue of Polyhedron)

CO2 superabsorption in a paddlewheel-type Ru dimer chain compound: Gate-open performance dependent on inter-chain interactions

Wataru Kosaka, Kayo Yamagishi, Hiroki Yoshida, Ryotaro Matsuda, Susumu Kitagawa, Masaki Takata, and Hitoshi Miyasaka

Chem. Commun., 2013, 49, 1594-1596. DOI:10.1039/C2CC36153A

Observation of two types of magnetization relaxation in a weakly correlated antiferromagnetic chain of MnIII2 single-molecule magnets

Hitoshi Miyasaka, Ayumi Saitoh, and Motohiro Nakano

Dalton Trans., 2012, 41, 13691-13696. (invited to the themed issue: Frontier and Perspectives in Molecule-Based Quantum Magnets)

Honeycomb frameworks with a very large mesh of 39 × 29 Å diameters stabilized by p-stacked coronene molecules

Tomonori Nozaki, Wataru Kosaka, Hitoshi Miyasaka

CrystEngComm, 2012, 14, 5398-5401. DOI: 10.1039/C2CE25806D

New Approach for Designing Single-Chain Magnets: Organization of Chains via Hydrogen Bonding between Nucleobases

Wei-Xiong Zhang, Takuya Shiga, Hitoshi Miyasaka, Masahiro Yamashita

J. Am. Chem. Soc., 2012, 134, 6908-6911. DOI: 10.1021/ja300152k

Effects of Pressure on Two-Dimensional Networked Single-Molecule Magnets exhibiting AC Field-Switchable Magnetic Properties

Masaki Mito, Masashi Ogawa, Hiroyuki Deguchi, Masahiro Yamashita, Hitoshi Miyasaka

J. Phys. Soc. Jpn., 2012, 81, 064716-1-6. DOI: 10.1143/JPSJ.81.064716

Coulombic Aggregations of MnIII Salen-Type Complexes and Keggin-Type Polyoxometalates: Isolation of Mn2 Single-Molecule Magnets

Yuki Sawada, Wataru Kosaka, Yoshihito Hayashi, and Hitoshi Miyasaka

Inorg. Chem., 2012, 51, 4824-4832.

An ionicity diagram for the family of [{Ru2(CF3CO2)4}2(TCNQRx)] (TCNQRx = R-substituted 7,7,8,8-tetracyanoquinodimethane)

Keita Nakabayashi, Masaki Nishio, Keiko Kubo, Wataru Kosaka, and Hitoshi Miyasaka

Dalton Trans., 2012, 41, 6072-6074.

Inorganic Frameworks Made by Combining Paddlewheel Diruthenium(II, III) Complexes and Polyoxometalate Clusters

Yuki Sawada, Yuma Yamamoto, Masaki Nishio, Wataru Kosaka, Yoshihito Hayashi, and Hitoshi Miyasaka

Chem. Lett., 2012, 41, 212-214.

Cyano-Bridged MnIII-MIII Single-Chain Magnets with MIII = CoIII, FeIII, MnIII, and CrIII

Hitoshi Miyasaka, Tomokura Madanbashi, Ayumi Saitoh, Natsuko Motokawa, Ryuta Ishikawa, Masahiro Yamashita, Stefan Bahr, Wolfgang Wernsdorfer, and Rodolphe Clérac

Chem. Eur. J., 2012, 18, 3942-3954.

A Dimer-of-Dimers Composed of Paddlewheel Diruthenium(II, III) Complexes and a Bridge of Tetrachlorohydroquinonate(2–) Devived by Intramolecular Charge Transfers

Masahisa Itoh, Yuichiro Asai, Hiromichi Kamo, Akira Miura, and Hitoshi Miyasaka

Chem. Lett., 2012, 41, 26-28.

Isolation of stable lacunary core of Dawson-type structure in a polyoxomolybdate cluster

Akihiro Hashikawa, Makiko Fujimoto, Yoshihito Hayashi, and Hitoshi Miyasaka

Chem. Commun., 2011, 47, 12361-12363.

Systematic Expansion of Supercubane Cores in Manganese Oxo Clusters with Tricarboxylate Ligands

Yayoi Okui, Florina Aurelia Catusanu, Ryoko Kubota, Bunsho, Kure, Takayuki Nakajima, Tomoaki Tanase, Takashi Kajiwara, Masahiro Mikuriya, Hitoshi Miyasaka, and Masahiro Yamashita

Eur. J. Inorg. Chem., 2011, 4325-4330.

Paramagnetic-Diamagnetic Phase Transition Accompanied by Coordination Bond Formation-Dissociation in the Dithiolate Complex Na[Ni(pdt)2]·2H2O

Shinya Takaishi, Nozomi Ishihara, Kazuya Kubo, Keiichi Katoh, Brian K. Breedlove, Hitoshi Miyasaka, and Masahiro Yamashita

Inorg. Chem., 2011, 50, 6405-6407.

Stepwise Neutral-Ionic Phase Transitions in a Covalently-Bonded Donor/Acceptor Chain Compound

Hitoshi Miyasaka, Natsuko Motokawa, Tamiko Chiyo, Miho Takemura, Masahiro Yamashita, Hajime Sagayama, and Taka-hisa Arima

J. Am. Chem. Soc., 2011, 133, 5338-5345.

Copper(II)-terbium(III) Single-Molecule Magnets linked by photochromic ligands

Takuya Shiga, Hitoshi Miyasaka, Masahiro Yamashita, Masakazu Morimoto, and Masahiro Irie

Dalton Trans., 2011, 40, 2275-2282.

Real time and space observation of domain wall migration in a MX-chain complex with a quasi-2D CDW state by using STM

Shinya Takaishi, Hashen Wu, Takashi Kajiwara, Brian K. Breedlove, Hitoshi Miyasaka, and Masahiro Yamashita

Dalton Trans., 2011, 40, 2160-2162.

Tuning of the ionization potential of paddlewheel diruthenium(II, II) complexes with fluorine atoms on the benzoate ligands

Hitoshi Miyasaka, Natsuko Motokawa, Ryo Atsuumi, Hiromichi Kamo, Yuichiro Asai, and Masahiro Yamashita

Dalton Trans., 2011, 40, 673-682.

A three-dimensional network of two-electron-transferred [Ru2]2TCNQ exhibiting anomalous conductance due to charge fluctuations

Hitoshi Miyasaka, Takaumi Morita, and Masahiro Yamashita

Chem. Commun., 2011, 47, 271-273 (invited paper for the theme issue: Emerging Investigators).

Low-temperature heat capacity of Sr8Ga16Ge30 and Ba8Ga16Ge30: Tunneling states and electron-phonon interaction in clathrates

Jingtao Xu, Jun Tang, Kazumi Sato, Yoichi Tanabe, Hitoshi Miyasaka, Masahiro Yamashita, Satoshi Heguri, and Katsumi Tanigaki

Phys. Rev. B, 2010, 82, 085206-1-5.

Magnetic/Conducting Bifunctionality due to π/σ Conjugated Functional Moieties in a Stacked Ferrimagnetic Chain

Hitoshi Miyasaka, Yuichiro Asai, Natsuko Motokawa, Kazuya Kubo and Masahiro Yamashita

Inorg. Chem., 2010, 49, 9116-9118.

ac field-switchable magnetic properties of two-dimensional networked nano-size magnets

Masaki Mito, Masashi Ogawa, Hiroyuki Deguchi, Masahiro Yamashita, and Hitoshi Miyasaka

J. Appl. Phys., 2010, 107, 124316-1-8.

Reversible Magnetism between an Antiferromagnet and a Ferromagnet Related to Solvation/Desolvation in a Robust Layered [Ru2]2TCNQ Charge-Transfer System

Natsuko Motokawa, Satoshi Matsunaga, Shinya Takaishi, Hitoshi Miyasaka, Masahiro Yamashita, and Kim R. Dunbar

J. Am. Chem. Soc., 2010, 132, 11943-11951.

Hybridized molecular materials based on [MnIII2] single molecule magnets with molecular conductors [Ni(dmit)2]n–

Kazuya Kubo, Hitoshi Miyasaka, Masahiro Yamashita

Physica B, 2010, 405, S313-S316.

Crystal structure and electrical conductivity of α’’’-[BEDT-TTF]12[Cu2Br4]3 (BEDT-TTF = bis(ethylenedithio)tetrathiafulvalene)

Kazuya Kubo, Hitoshi Miyasaka, Masahiro Yamashita

Physica B, 2010, 405, S308-S312.

Pressure effect on the three-dimensional charge-transfer ferromagnet [{Ru2(m-FPhCO2)4}2(BTDA-TCNQ)]

Natsuko Motokawa, Hitoshi Miyasaka, and Masahiro Yamashita

Dalton Trans., 2010, 39, 4724-4726 (invited paper for the theme issue: Molecular Magnets).

Structural Study of Electronic States in Quasi-One-Dimensional Halogen-Bridged Mixed-Metal Complexes [Ni1-xPdx(chxn)2Br]Br2

Shinya Takaishi, Hashen Wu, Jimin Xie, Takashi Kajiwara, Brian K. Breedlove, Hitoshi Miyasaka, and Masahiro Yamashita

Inorg. Chem., 2010, 49, 3694-3696.

Three-Dimensional Antiferromagnetic Order of Single-Chain Magnets: A New Approach to Design Molecule-Based Magnets

Hitoshi Miyasaka, Karin Takayama, Ayumi Saitoh, Sachie Furukawa, Masahiro Yamashita, and Rodolphe Clérac

Chem. Eur. J., 2010, 16, 3656-3662.

Structural, electronic and magnetic properties of Cu(II) complexes of 2-substituted tropones bearing ferrocenyl group at 5-position

Tohru Nishinaga, Tomoshi Aono, Eigo Isomura, Sayaka Watanabe, Yoshihiro Miyake, Akira Miyazaki, Toshiaki Enoki, Hitoshi Miyasaka, Hiroyuki Otani, and Masahiko Iyoda

Dalton Trans., 2010, 39, 2293-2300.

The Control of Charge-Transfer in a Series of Ru2II,II/TCNQ Two-Dimensional Networks by Tuning the Electron-Affinity of TCNQ Units: A Route to Synergistic Magnetic/Conducting Materials

Hitoshi Miyasaka, Natsuko Motokawa, Satoshi Matsunaga, Masahiro Yamashita, Kunihisa Sugimoto, Tatsuya Mori, Naoki Toyota, and Kim R. Dunbar

J. Am. Chem. Soc., 2010, 132, 1532-1544.

MnIII Salen-type Single-Molecule Magnet Fixed in a Two-dimensional Network

Chihiro Kachi-Terajima, Erina Mori, Tasuku Eiba, Toshiaki Saito, Chikahide Kanadani, Takafumi Kitazawa, and Hitoshi Miyasaka

Chem. Lett., 2010, 39, 94-95.

Water-Vapor-Induced Reversible Switching of Electronic States in an MMX-Type Chain Complex with Retention of Single Crystallinity

Hiroaki Iguchi, Shinya Takaishi, Hitoshi Miyasaka, Masahiro Yamashita, Hiroyuki Matsuzaki, Hiroshi Okamoto, Hisaaki Tanaka, and Shin-ichi Kuroda

Angew. Chem. Int. Ed., 2010, 49, 552-555.

Charge-transfer two-dimensional layers constructed from a 2:1 assembly of paddlewheel diruthenium(II, II) complexes and bis[1,2,5]thiadiazolotetracyanoquinodimethane: bulk magnetic behavior as a function of inter-layer interactions

Natsuko Motokawa, Tomomi Oyama, Satoshi Matsunaga, Hitoshi Miyasaka, Masahiro Yamashita and Kim R. Dunbar

CrystEngComm, 2009, 11, 2121-2130 (invited paper for the theme issue, Crystal Engineering in Molecular Magnetism)

Electroconductive Porous Coordination Polymer Cu[Cu(pdt)2] Composed of Donor and Acceptor Building Units

Shinya Takaishi, Miyuki Hosoda, Takashi Kajiwara, Hitoshi Miyasaka, Masahiro Yamashita, Yasuyuki Nakanishi, Yasutake Kitagawa, Kizashi Yamaguchi, Atsushi Kobayashi, Hiroshi Kitagawa

Inorg. Chem., 2009, 48, 9048-9050.

Ferromagnetic Assemblies Composed of MnIII Salen-Type Complexes and a Tripodal FeIII Complex with an Imidazolate Bridge

Ryuta Ishikawa, Hitoshi Miyasaka, and Masahiro Yamashita

Bull. Chem. Soc. Jpn., 2009, 82, 816-818.

Effect of an In-Plane Ligand on the Electronic Structures of Bromo-Bridged Nano-Wire Ni-Pd Mixed-Metal Complexes, [Ni1-xPdx(bn)2Br]Br2 (bn = 2S,3S-Diaminobutane)

Mari Sasaki, Hashen Wu, Daisuke Kawakami, Shinya Takaishi, Takashi Kajiwara, Hitoshi Miyasaka, Brian K. Breedlove, Masahiro Yamashita, Hideo Kishida, Hiroyuki Matsuzaki, Hiroshi Okamoto, Hisaaki Tanaka, and Shinichi Kuroda

Inorg. Chem., 2009, 48, 7446–7451.

Coordination Assemblies of [Mn4] Single-Molecule Magnets Linked by Photochromic Ligands: Photochemical Control of the Magnetic Properties

Masakazu Morimoto, Hitoshi Miyasaka, Masahiro Yamashita, Masahiro Irie

J. Am. Chem. Soc., 2009, 131, 9823–9835.

A Low-Temperature Scanning Tunneling Microscope Investigation of a Nonplanar Dysprosium-Phthalocyanine Adsorption on Au(111)

Y. Zhang, H. Isshiki, K. Katoh, Y. Yoshida, M. Yamashita, H. Miyasaka, B. K. Breedlove, T. Kajiwara, S. Takaishi, and T. Komeda

J. Phys. Chem. C, 2009, 113, 14407-14410.

Low-Temperature Scanning Tunneling Microscopy Investigation of Bis(phthalocyaninato)yttrium Growth on Au(111): From Individual Molecules to Two-Dimensional Domains

Yan Feng Zhang, Hironari Isshiki, Keiichi Katoh, Yusuke Yoshida, Masahiro Yamashita, Hitoshi Miyasaka, Brian K. Breedlove, Takashi Kajiwara, Shinya Takaishi, and Tadahiro Komeda

J. Phys. Chem. C, 2009, 113, 9826-9830.

Realization of a Magnet Using an Antiferromagnetic Phase of Single Chain Magnets

Claude Coulon, Rodolphe Clérac, Wolfgang Wernsdorfer, Thierry Colin, and Hitoshi Miyasaka

Phys. Rev. Lett., 2009, 102, 167204-1-4.

Slow dynamics of the magnetization in one-dimensional coordination polymers: Single-Chain Magnets

Hitoshi Miyasaka, Miguel Julve, Masahiro Yamashita, Rodolphe Clérac

Inorg. Chem., 2009, 48, 3420-3437 (Forum Issue for Molecular Magnetism; invited paper).

[MIII(dmit)2]––Coordinated MnIII Salen-Type Dimers (MIII = NiIII, AuIII; dmit2- = 1,3-Dithiol-2-thione-4,5-dithiolate): Design of Single-Component Conducting Single-Molecule Magnet–Based Materials

Hiroki Hiraga, Hitoshi Miyasaka, Rodolphe Clérac, Marc Fourmigué, and Masahiro Yamashita

Inorg. Chem., 2009, 48, 2887-2898.

Direct Synthesis and Crystal Structure of Dehydrated State in Vapochromic MMX-type Quasi-One-Dimensional Iodide-Bridged Platinum Complexes

Hiroaki Iguchi, Shinya Takaishi, Takashi Kajiwara, Hitoshi Miyasaka, Masahiro Yamashita, Hiroyuki Matsuzaki, Hiroshi Okamoto

J. Inorg. Organomet. Polym., 2009, 19, 85-90.

Mixed Charge-Ordering State of MMX-Type Quasi-One-Dimensional Iodide-Bridged Platinum Complexes with Binary Counterions

Hiroaki Iguchi, Shinya Takaishi, Takashi Kajiwara, Hitoshi Miyasaka, Masahiro Yamashita, Hiroyuki Matsuzaki, Hiroshi Okamoto

J. Am. Chem. Soc., 2008, 130, 17668-17669.

Long-distance ferromagnetic coupling through spin polarization in a linear heterotrinuclear iron(III)-copper(II)-iron(III) complex derived from 5-ferrocenyl-2-aminotropone

Yoshihiro Miyake, Sayaka Watanabe, Satoshi Aono, Tohru Nishinaga, Akira Miyazaki, Toshiaki Enoki, Hitoshi Miyasaka, Hiroyuki Otani, Masahiko Iyoda

Chem. Commun., 2008, 6167-6169.

Magnetic-Field-Induced Freezing of Spin Correlations in Networked System of [Mn4] Single-Molecule Magnets

Satoshi Yamashita, Tatsuya Fujisaki, Yasuhiro Nakazawa, Masaharu Oguni, Kazuya Nakata, Masahiro Yamashita, and Hitoshi Miyasaka

J. Phys. Soc. Jpn., 2008, 77, 073708.

An Electron-Transfer Ferromagnet with Tc = 107 K Based on a Three-Dimensional [Ru2]2/TCNQ System

Natsuko Motokawa, Hitoshi Miyasaka, Masahiro Yamashita, Kim R. Dunbar

Angew. Chem. Int. Ed., 2008, 47, 7760-7763.

Charge-Dencity-Wave to Mott-Hubbard Phase Transition in Quasi-One-Dimensional Bromo-Bridged Pd Compounds

Shinya Takaishi, Mitsuhito Takamura, Takashi Kajiwara, Hitoshi Miyasaka, Masahiro Yamashita, Muneaki Iwata, Hiroyuki Matsuzaki, Hiroshi Okamoto, Hisaaki Tanaka, Shin-ichi Kuroda, Hiroyuki Nishikawa, Hiroki Oshio, Kenichi Kato, and Masaki Takata

J. Am. Chem. Soc., 2008, 130, 12080-12084.

Hybridized complexes of [MnIII2] Single-Molecule Magnets and Ni dithiolate complexes

Hiroki Hiraga, Hitoshi Miyasaka, Shinya Takaishi, Takashi Kajiwara, Masahiro Yamashita

Inorg. Chim. Acta, 2008, 361, 3863-3872.

A ladder based on paddlewheel diruthenium(II, II) rails connected by TCNQ rungs: a polymorph of the hexagonal 2-D network phase

Natsuko Motokawa, Tomomi Oyama, Satoshi Matsunaga, Hitoshi Miyasaka, Kunihisa Sugimoto, Masahiro Yamashita, Nazario Lopez and Kim R. Dunbar

Dalton Trans., 2008, 4099-4102.

Three-Dimensionally Ordered CDW State in Quasi-One-Dimensional Iodo-Bridged Dinuclear Platinum Mixed-Valence Compounds, A4[Pt2I(pop)4]·nH2O (A = Aromatic Ammonium Cations)

Satoshi Matsunaga, Kouichi Takizawa, Daisuke Kawakami, Hiroaki Iguchi, Shinya Takaishi, Takashi Kajiwara, Hitoshi Miyasaka, Masahiro Yamashita, Hiroyuki Matsuzaki, and Hiroshi Okamoto

Eur. J. Inorg. Chem., 2008, 3269-3273.

A MnIII2NiII single-chain magnet separated by a thick isolating network of BPh4- anions

Hitoshi Miyasaka, Ayumi Saitoh, Masahiro Yamashita, and Rodolphe Clérac

Dalton Trans., 2008, 2422-2427.

One-dimensional coordination polymers of antiferromagnetically-coupled [Mn4] single-molecule magnets

Lollita Lecren, Olivier Roubeau, Yang-Guang Li, Xavier F. Le Goff, Hitoshi Miyasaka, Florent Richard, Wolfgang Wernsdorfer, Claude Coulon, and Rodolphe Clérac

Dalton Trans., 2008, 755-766.

Two-Dimensional Coordination Networks of [Mn4] Single-Molecule Magnets: Heat Capacity Measurements

Tatsuya Fujisaki, Yasuhiro Nakazawa, Masaharu Oguni, Kazuya Nakata, Masahiro Yamashita, Lollita Lecren, and Hitoshi Miyasaka

J. Phys. Soc. Jpn., 2007, 76, 104602-1-5.

Effect of an applied magnetic field on the relaxation time of single-chain magnets

Claude Coulon, Rodolphe Clérac, Wolfgang Wernsdorfer, Rhierry Colin, Ayumi Saitoh, Natsuko Motokawa, and Hitoshi Miyasaka

Phys. Rev. B, 2007, 76, 214422-1-15.

Hybrid Molecular Material Exhibiting Single-Molecule Magnet Behavior and Molecular Conductivity

Hiroki Hiraga, Hitoshi Miyasaka, Kazuya Nakata, Takashi Kajiwara, Shinya Takaishi, Yugo Oshima, Hiroyuki Nojiri and Masahiro Yamashita

Inorg. Chem., 2007, 46, 9661-9671.

Why Does the Disorder of R-pn and rac-pn Ligands in the Quasi-One-Dimensional Bromo-Bridged NiIII Complexes, [Ni(pan)2Br]Br2 (pn = 1,2-diaminopropane) Afford Similar STM Patterns?

Hashen Wu, Daisuke Kawakami, Mari Sasaki, Jimin Xie, Shinya Takaishi, Takashi Kajiwara, Hitoshi Miyasaka, Masahiro Yamashita, Hiroyuki Mtsuzaki, and Hiroshi Okamoto

Inorg. Chem., 2007, 46, 7410-7413.

Metal-Insulator Transition of Charge-Transfer Salts Based on Unsymmetrical Donor DMET and Metal Halide Anions (DMET)4(MCl4)(TCE)2 (M = Mn, Co, Cu, Zn; TCE = 1,1,2,-trichloroethane)

Hiroshi Ito, Daichi Suzuki, Harutaka Watanabe, Hisaaki Tanaka, Shin-ichi Kuroda, Masamichi Umemiya, Norihito Kobayashi, Makoto Goto, Ken-ichi Sugiura, Hitoshi Miyasaka, Shinya Takaishi, Takashi Kajiwara, Masahiro Yamashita, Eiji Ohmichi, and Toshihito Osada

J. Am. Chem. Soc., 2007, 129, 8510-8518.

Single-Molecule Magnet Behavior in Heterometallic MII–MnIII2–MII Tetramers (MII = Cu, Ni) Containing MnIII Salen-Type Dinuclear Core

Chihiro Kachi-Terajima, Hitoshi Miyasaka, Ayumi Saitoh, Naoki Shirakawa, Masahiro Yamashita, and Rodolphe Clérac

Inorg. Chem., 2007, 46, 5861-5872.

Pressure effects on Mn4 single-molecule magnet with two-dimensional correlation

M. Ogawa, M. Mito, T. Tajiri, H. Deguchi, S. Takagi, K. Nakata, M. Yamashita, and H. Miyasaka

J. Mag. Mag. Mater., 2007, 310, e489-e491.

Unusual regioselective mercuration of metalloporphyrins and its potential applications

Ken-ichi Sugiura, Aiko Kato, Kentaro Iwasaki, Hitoshi Miyasaka, Masahiro Yamashita, Shojun Hino and Dennis P. Arnold

Chem. Commun., 2007, 2046-2047.

Direct evidence of exchange interaction dependence of magnetization relaxation in a family of ferromagnetic-type single-chain magnets

Ayumi Saitoh, Hitoshi Miyasaka, Masahiro Yamashita, and Rodolphe Clérac

J. Mater. Chem., 2007, 17, 2002-2012 (Hot paper).

One-Dimensional Supramolecular Organization of Single-Molecule Magnets

Lollita Lecren, Wolfgang Wernsdorfer, Yang-Guang Li, Alessandro Vindigni, Hitoshi Miyasaka, and Rodolphe Clérac

J. Am. Chem. Soc., 2007, 129, 5045-5051.

Tuning of Electronic Structures of Quasi-One-Dimensional Bromo-Bridged PdII-PdIV Mixed-Valence Complexes by Substituting Counter Anions

Hisamitsu Arakawa, Daisuke Kawakami, Shinya Takaishi, Takashi Kajiwara, Hitoshi Miyasaka, Ken-ichi Sugiura, Masahiro Yamashita, Hideo Kishida, and Hiroshi Okamoto

Bull. Chem. Soc. Jpn., 2007, 80, 189-191.

Giant Macrocycles Composed of Thiophene, Acetylene, and Ethylene Building Blocks

Kazumi Nakao, Masayuki Nishimura, Tomoya Tamachi, Yoshiyuki Kuwatani, Hitoshi Miyasaka, Tohru Nishinaga, and Masahiko Iyoda

J. Am. Chem. Soc., 2006, 128, 16740-16747.

Spin correlation and relaxational dynamics in molecular-based single-chain magnets

Jun-ichiro Kishine, Tomonari Watanabe, Hiroyuki Deguchi, Masaki Mito, Toru Sakai, Takayuki Tajiri, Masahiro Yamashita, and HitoshiMiyasaka

Phys. Rev. B, 2006, 74, 224419-1-7.

Single-Chain Magnet Behavior in an Alternated One-Dimensional Assembly of MnIII Schiff-Base Complex and TCNQ Radical

Hitoshi Miyasaka, Tomokura Madanbashi, Kunihisa Sugimoto, Yasuhiro Nakazawa, Wolfgang Wernsdorfer, Ken-ichi Sugiura, Masahiro Yamashita, Claude Coulon, and Rodolphe Clérac

Chem. Eur. J., 2006, 12, 7028-7040.

Versatile Vapochromic Behavior Accompanied by a Phase Change between Charge-Polarization State and Charge-Density-Wave State in a Quasi-One-Dimensional Iodo-Bridged Dinuclear Platinum Mixed-Valence Compound, [{NH3(CH2)5NH3}2][Pt2(pop)4I]·4H2O

Masahiro Yamashita, Kouichi Takamizawa, Satoshi Matsunaga, Daisuke Kawakami, Hiroaki Iguchi, Shinya Takaishi, Takashi Kajiwara, Fumiyasu Iwahori, Tomohiko Ishii, Hitoshi Miyasaka, Ken-ichi Sugiura, Hiroyuki Matsuzaki, Hideo Kishida, and Hiroshi Okamoto

Bull. Chem. Soc. Jpn., 2006, 79, 1404-1406.

Long-Range Ordered Magnet of a Charge-Transfer Ru24+/TCNQ Two-Dimensional Network Compound

Hitoshi Miyasaka, Toru Izawa, Nao Takahashi, Masahiro Yamashita, and Kim R. Dunbar

J. Am. Chem. Soc., 2006, 128, 11358-11359.

Observation of the Collective Magnetic Excitation in the Single-Chain Magnet

Yugo Oshima, Hiroyuki Nojiri, Kaname Asakura, Toru Sakai, Masahiro Yamashita, and Hitoshi Miyasaka

Phys. Rev. B, 2006, 73, 214435-1-5.

From ST = 3 Single-Molecule Magnet to Diamagnetic Ground State Depending on Molecular Packing of MnIII Salen-type Dimers Decorated by N,N'-Dicyano-1,4-naphthoquinonediiminate Radicals

Chihiro Kachi-Terajima, Hitoshi Miyasaka, Ken-ichi Sugiura, Rodolphe Clérac, and Hiroyuki Nojiri

Inorg. Chem., 2006, 45, 4381-4390.

Dynamical Valence Fluctuation at the Charge-Density-Wave Phase Boundary in Iodide-Bridged Pt Compound [Pt(chxn)2I]I2

Shinya Takaishi, Daisuke Kawakami, Masahiro Yamashita, Mari Sasaki, Takashi Kajiwara, Hitoshi Miyasaka, Ken-ichi Sugiura, Yusuke Wakabayashi, Hiroshi Sawa, Hiroyuki Matsuzaki, Hideo Kishida, Hiroshi Okamoto, Harutaka Watanabe, Hisaaki Tanaka, Kazuhiro Marumoto, Hiroshi Ito, and Shin-ichi Kuroda

J. Am. Chem. Soc., 2006, 128, 6420-6425.

Two-Dimensional Networks Based on Mn4 Complex Linked by Dicyanamide Anion: From Single-Molecule Magnet to Classical Magnet Behavior

Hitoshi Miyasaka, Kazuya Nakata, Lollita Lecren, Claude Coulon, Yasuhiro Nakazawa, Tatsuya Fujisaki, Ken-ichi Sugiura, Masahiro Yamashita, and Rodolphe Clérac

J. Am. Chem. Soc., 2006, 128, 3770-3783.

Metal-Metal Bonded Diruthenium Unit Axial-Capped by Di-tert-butylphenolate: [Ru2(O2CCH3)2(t-Busal-R’py)2]- (t-Busal-R’py2- = N-(R’-2-pyridyl)-2-oxy-3,5-di-tert-butylbenzylaminate; R’ = H, 4-Me, 5-Me)

Hitoshi Miyasaka, Toru Izawa, Shinya Takaishi, Kunihisa Sugimoto, Ken-ichi Sugiura, and Masahiro Yamashita

Bull. Chem. Soc. Jpn., 2006, 79, 612-620.

New Charge-transfer Salts Based on Unsymmetrical Donor DMET and Metal Complex Anions: (DMET)3[Cr(isoq)2(NCS)4] and (DMET)3[Cr(phen)(NCS)4]·CH3CN

Masamichi Umemiya, Makoto Goto, Narihito Kobayashi, Shinya Takaishi, Takashi Kajiwara, Masahiro Yamashita, Hitoshi Miyasaka, Ken-ichi Sugiura, Harutaka Watanabe, Daichi Suzuki, Hiroshi Ito, and Shin-ichi Kuroda

Chem. Lett., 2006, 135, 368-369.

Slow relaxation in a one-dimensional rational assembly of antiferromagnetically-coupled [Mn4] single-molecule-magnets

Lollita Lecren, Olivier Roubeau, Claude Coulon, Yang-Guang Li, Xavier Le Goff, Worfgang Wernsdorfer, Hitoshi Miyasaka, and Rodolphe Clérac

J. Am. Chem. Soc., 2005, 127, 17353-17363.

Quantum nucleation in a single-chain magnet

Wolfgang Wernsdorfer, Rodolphe Clérac, Claude Coulon, Lollita Lecren, and Hitoshi Miyasaka

Phys. Rev. Lett., 2005, 95, 237203-1-4.

Effect of pressure on single-chain magnets with repeating units of the MnIII-NiII-MnIII trimer

Masaki Mito, Hiroyuki Deguchi, Takayuki Tajiri, Seishi Takagi, Masahiro Yamashita, and Hitoshi Miyasaka

Phys. Rev. B., 2005, 72, 144421-1-144421-9.

Syntheses, crystal structures and magnetic properties of Mn12 single-molecule magnets with diphenylphosphate and their tetraphenylphosphonium salts

Takayoshi Kuroda-Sowa, Guo-Qing Bian, Masaki Hatano, Hisashi Konaka, Satoshi Fukuda, Shinsuke Miyoshi, Masahiko Maekawa, Megumu Munakata, Hitoshi Miyasaka and Masahiro Yamashita

Polyhedron, 2005, 24, 2680-2690.

A mixed-valence Mn6 cluster capped by nitronyl nitroxide units

Kazuya Nakata, Hitoshi Miyasaka, Fumiyasu Iwahori, Ken-ichi Sugiura, Masahiro Yamashita

Polyhedron, 2005, 24, 2250-2256.

Syntheses, Crystal Structure, and Magnetic Properties of Mn12 Single-Molecule Magnets with Naphthalenecarboxylate Bridges, [Mn12O12(O2CC10H7)16(H2O)4] and Their Tetraphenylphosphonium Salts

Guo-Qing Bian, Takayoshi Kuroda-Sowa, Tadahiro Nogami, Kunihisa Sugimoto, Masahiko Maekawa, Megumu Munakata, Hitoshi Miyasaka, and Masahiro Yamashita

Bull. Chem. Soc. Jpn., 2005, 78, 1032-1039.

Synthetic Strategy for Rational Design of Single-Chain Magnets

Hitoshi Miyasaka and Rodolphe Clérac

Bull. Chem. Soc. Jpn., 2005, 78, 1725-1748 (Award Accounts).

Cyano-bridged MnIII3MIII (MIII = Fe, Cr) Complexes: Synthesis, Structure, and Magnetic Properties

Hitoshi Miyasaka, Hitomi Takahashi, Tomokura Madanbashi, Ken-ichi Sugiura, Rodolphe Clérac, Hiroyuki Nojiri

Inorg. Chem., 2005, 44, 5969-5971.

Quantum Tunneling and Quantum Phase Interference in a [MnII2MnIII2] Single-Molecule Magnet

Lollita Lecren, Wolfgang Wernsdorfer, Yang-Guang Li, Olivier Roubeau, Hitoshi Miyasaka, and Rodolphe Clérac

J. Am. Chem. Soc., 2005, 127, 11311-11317.

Nichel(II) and iron(II) mononuclear complexes with 1-methylimidazole-2-aldoximate: new building units for molecule-assembled magnetic materials

Hitoshi Miyasaka, Ayumi Saitoh, Sayaka Yanagida, Chihiro Kachi-Terajima, Ken-ichi Sugiura, Masahiro Yamashita

Inorg. Chimi. Acta, 2005, 358, 3525-3535.

[Mn4(hmp)6(CH3CN)2(H2O)4]4+: A new single-molecule magnet with the highest blocking temperature in the Mn4/hmp family of compounds

Lollita Lecren, Yang-Guang Li, Wolfgang Wernsdorfer, Olivier Roubeau, Hitoshi Miyasaka, and Rodolphe Clérac

Inorg. Chem. Commun., 2005, 8, 626-630.

Heat capacity and magnetic phase transition of two-dimensional metal-assembled complex, K[{MnIII(3-MeOsalen)}2FeIII(CN)6]

Yuji Miyazaki, Qi Wang, Qing-sen Yu, Tetsuya Matsumoto, Hitoshi Miyasaka, Naohide Matsumoto, and Michio Sorai

Thermochimica Acta, 2005, 431, 133-137.

Vapochromic Behavior Accompanied by Phase Transition between Charge-Polarization and Charge-Density-Wave States in a Quasi-One-Dimensional Iodine-Bridged Dinuclear Platinum Compound

Hiroyuki Matsuzaki, Hideo Kishida, Hiroshi Okamoto, Kouichi Takizawa, Satoshi Matsunaga, Shinya Takaishi, Hitoshi Miyasaka, Ken-ichi Sugiura, and Masahiro Yamashita

Angew. Chem. Int. Ed., 2005, 44, 2-5.

Single-Chain Magnet (NEt4)[Mn2(5-MeOsalen)2Fe(CN)6] Made of MnIII-FeIII-MnIII Trinuclear Single-Molecule Magnet with an ST = 9/2 Spin Ground State

Marilena Ferbinteanu, Hitoshi Miyasaka, Wolfgang Wernsdorfer, Kazuya Nakata, Ken-ichi Sugiura, Masahiro Yamashita, Claude Coulon, and Rodolphe Clérac

J. Am. Chem. Soc., 2005, 127, 3090-3099.

[MnIII2(5-Rsaltmen)2NiII(pao)2(L)]2+: An ST = 3 Building-Block for Single-Chain Magnet That Behaves as a Single-Molecule Magnet

Hitoshi Miyasaka, Tomohiro Nezu, Kunihisa Sugimoto, Ken-ichi Sugiura, Masahiro Yamashita, and Rodolphe Clérac

Chem. Eur. J., 2005, 11, 1592-1602.

Electrical Conduction in Divalent BEDT-TTF Salts

H. Ito, Y. Yokochi, H. Tanaka, S. Kuroda, R. Kanehama, M. Umemiya, H. Miyasaka, K. Sugiura, and M. Yamashita

Synth. Metals, 2005, 153, 441-444.

Quasi-one-dimensional electronic structure of (DMET)2CuCl2

H. Ito, D. Suzuki, Y. Yokochi, S. Kuroda, M. Umemiya, H. Miyasaka, K. Sugiura, M. Yamashita, and H. Tajima

Phys. Rev. B, 2005, 71, 212503-1-4.

Charge carriers in the divalent conductor (BEDT-TTF)Cu2Br4

H. Ito, Y. Yokochi, H. Tanaka, S. Kuroda, R. Kanehama, M. Umemiya, H. Miyasaka, K.-I. Sugiura, M. Yamashita, H. Tajima, and J. Yamaura

Phys. Rev. B, 2005, 71, 085202.

Framework Control by a Metalloligand Having Multicoordination Ability: New Synthetic Approach for Crystal Structures and Magnetic Properties

Shin-ichiro Noro, Hitoshi Miyasaka, Susumu Kitagawa, Tatsuo Wada, Takashi Okubo, Masahiro Yamashita, and Tadaoki Mitani

Inorg. Chem., 2005, 44, 133-146.

New organic conductor (DMET)2CuCl2: synthesis, structure and physical properties

M. Umemiya, K. Goto, S. Takaishi, H. Miyasaka, K. Sugiura, M. Yamashita, H. Nishikawa, K. Kikuchi, I. Ikemoto, Y. Yokochi, H. Ito, and S. Kuroda

J. Phys. IV France, 2004, 114, 589.

[{[Pt(en)2][PtX2(en)2]}3][{MX5}X3]2]·12H2O: Quasi-One-Dimensional, Halogen-Bridged PtII-PtIV Mixed-Valence Compounds with Magnetic Counteranions

Masahiro Yamashita, Daisuke Kawakami, Satoshi Matsunaga, Yoshio Nakayama, Mari Sasaki, Shinya Takaishi, Fumiyasu Iwahori, Hitoshi Miyasaka, Ken-ichi Sugiura, Yoshiki Wada, Hiroshi Miyamae, Hiroyuki Matsuzaki, Hiroshi Okamoto, Hisaaki Tanaka, Kazuhiro Marumoto, and Shin-ichi Kuroda

Angew. Chem. Int. Ed., 2004, 43, 4763-4767.

Linear NiII-MnIII2-NiII Tetramers: Oligomeric Species of the MnIII2NiII Single-Chain Magnets

Hitoshi Miyasaka, Tomohiro Nezu, Kunihisa Sugimoto, Ken-ichi Sugiura, Masahiro Yamashita, and Rodolphe Clérac

Inorg. Chem., 2004, 43, 5486-5488.

Pressure effects on single chain magnets

M. Mito, N. Shindo, T. Tajiri, H. Deguchi, S. Takagi, H. Miyasaka, M. Yamashita, R. Clérac, C. Coulon

J. Mag. Mag. Mater., 2004, 272-276, 1118-1119.

A Novel Mn12 Single-molecule Magnet with a 3-Methanesulfonate Bridge

Takayoshi Kuroda-Sowa, Tetsuji Handa, Takehiro Kotera, Masahiko Maekawa, Megumu Munakata, Hitoshi Miyasaka, and Masahiro Yamashita

Chem. Lett., 2004, 33, 540-541

A Mn12 Single-Molecule Magnet [Mn12O12(OAc)12(dpp)4] (dppH = Diphenyl Phosphate) with No Coordinating Water Molecules

Guo-Qing Bian, Takayoshi Kuroda-Sowa, Hisashi Konaka, Masaki Hatano, Masahiko Maekawa, Megumu Munakata, Hitoshi Miyasaka, and Masahiro Yamashita

Inorg. Chem., 2004, 43, 4790-4792.

A Dinuclear Ruthenium(II) Chelating Amido Complex: Synthesis, Characterization, and Coupling Reaction with Carbon Monoxide

Shin Takemoto, Shinya Oshio, Tomoharu Kobayashi, Hiroyuki Matsuzaka, Masatsugu Hoshi, Hironobu Okimura, Masayo Yamashita, Hitoshi Miyasaka, Tomohiko Ishii, and Masahiro Yamashita

Organometallics, 2004, 23, 3587-3589.

Visualization of Local Valence Structures in Quasi-One-Dimensional Halogen-Bridged Complexes [Ni1-xPdx(chxn)2Br]Br2 by STM

Shinya Takaishi, Hitoshi Miyasaka, Ken-ichi Sugiura, Masahiro Yamashita, Hiroyuki Matsuzaki, Hideo Kishida, Hiroshi Okamoto, Hisaaki Tanaka, Kazuhiro Marumoto, Hiroshi Ito, Shin-ichi Kuroda, and Tomohide Takami

Angew. Chem. Int. Ed., 2004, 43, 3171-3175.

Dimeric Manganese(III) Tetradentate Schiff-Base Complex as a Single-Molecule Magnet

Hitoshi Miyasaka, Rodolphe Clérac, Wolfgang Wernsdorfer, Lollita Lecren, Claire Bonhomme, Ken-ichi Sugiura and Masahiro Yamashita

Angew. Chem. Int. Ed., 2004, 43, 2801-2805.

Glauber dynamics in a single-chain magnet: From theory to real systems

Claude Coulon, Rodolphe Clérac, Lollita Lecren, Wolfgang Wernsdorfer, and HitoshiMiyasaka

Phys. Rev. B, 2004, 69, 132408-1-132408-4.

A Square Cyclic Porphyrin Dodecamer: Synthesis and Single-Molecule Characterization

Aiko Kato, Ken-ichi Sugiura, Hitoshi Miyasaka, Hiroyuki Tanaka, Tomoji Kawai, Manabu Sugimoto, and Masahiro Yamashita

Chem. Lett., 2004, 33, 578-579.

Racemic nickel(II) pyridine-2-aldoximate complexes capped by 2,2’-bipyridine and 1,10-phenanthroline: syntheses, structures and magnetic properties

Hitoshi Miyasaka, Sachie Furukawa, Sayaka Yanagida, Ken-ichi Sugiura, and Masahiro Yamashita

Inorg. Chimi. Acta, 2004, 357, 1619-1626.

A Three-Dimensional Ferrimagnet Composed of Mixed-Valence Mn4 Clusters Linked by an {Mn[N(CN)2]6}4- Unit

Hitoshi Miyasaka, Kazuya Nakata, Ken-ichi Sugiura, Masahiro Yamashita, and Rodolphe Clérac

Angew. Chem. Int. Ed., 2004, 43, 707-711.

Novel ET-Coordinated Copper(I) Complexes: Synthese, Structures, and Physical Properties (ET = BEDT-TTF = Bis(ethylenedithio)tetrathiafulvalene)

Ryo Kanehama, Masamichi Umemiya, Fumiyasu Iwahori, Hitoshi Miyasaka, Ken-ich Sugiura, Masahiro Yamashita, Yasukata Yokochi, Hiroshi Ito, Shin-ichi Kuroda, Hideo Kishida, and Hiroshi Okamoto

Inorg. Chem., 2003, 42, 7173-7181.

13C NMR Spectra, 1H NMR Relaxation and ESR Measurements of Br2 Doped {[Pt(en)2][PtBr2(en)2]}3(CuBr4)4·12H2O

N. Kimura, H. Aso, K. Takizawa, T. Ishii, H. Miyasaka, K. Sugiura, M. Yamashita, and R. Ikeda

Synth. Metals, 2003, 135-136, 271-272.

Pyrene-Fused Porphyrins: Annulation Reactions of meso-Pyrenylporphyrins

Osamu Yamane, Ken-ichi Sugiura, Hitoshi Miyasaka, Kazuya Nakamura, Tatsuhiko Fujimoto, Kazuki Nakamura, Takahiro Kaneda, Toshiteru Sakata, and Masahiro Yamashita

Chem. Lett., 2003, 33, 40-41.

[Mn2(saltmen)2Ni(pao)2(L)2](A)2 with L = pyridine, 4-picoline, 4-t-butylpyridine, N-methylimidazole and A = ClO4-, BF4-, PF6-, ReO4-:A Family of Single-Chain Magnet

Hitoshi Miyasaka, Rodolphe Clérac, Kaori Mizushima, Ken-ichi Sugiura, Masahiro Yamashita, Wolfgang Wernsdorfer, and Claude Coulon

Inorg. Chem., 2003, 42, 8203-8213.

Carrier Doping Effect into Quasi-One-Dimensional Bromo-Bridged Ni(III) Complexes with Strong Electron-Correlation by Cu(II) Ions, [Ni1-xCux(chxn)2Br]Br2-x

Masahiro Yamashita, Takashi Ono, Satoshi Matsunaga, Mari Sasaki, Shinya Takaishi, Fumiyasu Iwahori, Hitoshi Miyasaka, Ken-ichi Sugiura, Hideo Kishida, Hiroshi Okamoto, Hisaaki Tanaka, Yasuhisa Hasegawa, Kazuhiro Marumoto, Hiroshi Ito, Sin-ichi Kuroda, and Noriyoshi Kimura

Inorg. Chem., 2003, 42, 7692-7694.

A Family of Diruthenium Compounds with Dianionic Tridentate Ligands of N-(2-pyridyl)-2-oxy-5-R-benzylaminate (R = H, Me, Cl, Br, NO2): Isolation, Structure Determination and Electrochemistry

Hitoshi Miyasaka, Toru Izawa, Ken-ichi Sugiura, and Masahiro Yamashita

Inorg. Chem., 2003, 42, 7683-7690.

Synthesis and Structural Determination of a Porphyrinatoplatinum(II): meso-Tetrakis(4-t-butylphenyl)porphyrinatoplatinum(II)

Masamichi Umemiya, Ken-ichi Sugiura, Hitoshi Miyasaka, Tomohiko Ishii, and Masahiro Yamashita

Bull. Chem. Soc. Jpn., 2003, 76, 2123-2127.

Synthesis, crystal structure and magnetic properties of novel Mn12 single-molecule magnets with thiophenecarboxylate, [Mn12O12(O2CC4H3S)16(H2O)4], and its tetraphenylphosphonium salt

Takayoshi Kuroda-Sowa, Tadahiro Nogami, Hisashi Konaka, Masahiko Maekawa, Megumu Munakata, Hitoshi Miyasaka, and Masahiro Yamashita

Polyhedron, 2003, 22, 1795-1801.

Heterometallic Hexanuclear Cluster with an S = 8 Spin Ground State: MnII{MnII(hfac)2}3{NiII(pao)3}2 (hfac- = Hexafluoroacethylacetonate, pao- = Pyridine-2-aldoximate)

Hitoshi Miyasaka, Tomohiro Nezu, Fumiyasu Iwahori, Sachie Furukawa, Kunihisa Sugimoto, Rodolphe Clérac, Ken-ichi Sugiura, and Masahiro Yamashita

Inorg. Chem., 2003, 42, 4501-4503.

A Unique Diruthenium(II, III) Unit Surrounded by Tridentate Ligands of N-(2-Pyridyl)-2-oxy-5-chlorobenzylaminate

Hitoshi Miyasaka, Ken-ichi Sugiura, Masahiro Yamashita

Inorg. Chem. Commun., 2003, 6, 1078-1080.

Systematic Synthesis of Porphyrin Dimers Linked by Conjugated Oligoacetylene Bridges

Kazuya Nakamura, Tatsuhiko Fujimoto, Satoshi Takara, Ken-ichi Sugiura, Hitoshi Miyasaka, Tomohiko Ishii, Masahiro Yamashita, and Yoshiteru Sakata

Chem. Lett., 2003, 32, 694-695.

Structure and Magnetic Properties of the Two-Dimensional Ferrimagnet, (NEt4)[{Mn(salen)}2Fe(CN)6]: Investigation of Magnetic Anisotropy on a Single Crystal

Hitoshi Miyasaka, Hidenori Ieda, Naohide Matsumoto, Ken-ichi Sugiura, and Masahiro Yamashita

Inorg. Chem., 2003, 42, 3509-3515.

Platinum(II) Complex with S = 1/2 Organic Radical Ligand

F. Iwahori, H. Miyasaka, T. Ishii, K. –i. Sugiura, and M. Yamashita

Synth. Metals, 2003, 135-136, 355-356.

Tuning of spin density wave strength of Ni(III) complexes with strong electron-correlation

T. Ono, M. Yamashita, K. Yokoyama, S. Furukawa, T. Manabe, K. Sugiura, T. Ishii, H. Miyasaka, H. Matsuzaki, H. Kishida, H. Okamoto, K. Marumoto, H. Tanaka, Y. Hasegawa, S. Kuroda, and H. Itou

Synth. Metals, 2003, 135-136, 357-358.

New charge-transfer salts (ET)8(MnIIBr4)2(DCE)2 and (ET)3MnIIBr4: Preparations, structures and physical properties (ET = BEDT-TTF, DCE = 1,2-dichloroethane)

R. Kanehama, H. Miyasaka, K. Sugiura, M. Yamashita, H. Itou, S. Kuroda, H. Kishida, and H. Okamoto

Synth. Metals, 2003, 135-136, 633-634.

A series of Ni(II) pyridyloximato (pao-) compounds [Ni(pao)2(L)2] (L = unidentate ligand): as a coordination donor

building block in the assembly with Mn(III) salen analogues

Hitoshi Miyasaka, Kaori Mizushima, Ken-ichi Sugiura, and Masahiro Yamashita

Synth. Metals, 2003, 137, 1245-1246.

Syntheses and physical properties of new charge-transfer salts consisting of a conducting BEDT-TTF column and magnetic 1D or 2D Fe(III) networks

R. Kanehama, Y. Yoshino, T. Ishii, T. Manabe, H. Hara, H. Miyasaka, H. Matsuzaka, M. Yamashita, M. Katada, H. Nishikawa, I. Lkemoto

Synth. Metals, 2003, 133-134, 553-554.

Unprecedented Soliton Formation Mechanism in Quasi-One-Dimensional Chloro-Bridged PtII-PtIV Mixed-Valence Compound, {[Pt(en)2][PtCl2(en)2]}3(CuCl4)4·12H2O

Masahiro Yamashita, Hidemitsu Aso, Satoshi Matsunaga, Koichi Takizawa, Kazuya Nakata, Chihiro Kachi-Terajima, Fumiyasu Iwahori, Tomohiko Ishii, Hitoshi Miyasaka, Ken-ichi Sugiura, Takuya Kawashima, Kenzi Takai, Noritaka, Kuroda, Motoo Shiro, Hideo Kishida, Hiroshi Okamoto, Hiroyuki Takahashi, Hisaaki Tanaka, Kazuhiro Marumoto, and Shin-ichi Kuroda

Chem. Lett., 2003, 32, 278-279.

Evidence for Single Chain Magnet Behavior in a MnIII-NiII Chain Desighed with High Spin Magnetic Units: A Route to High Temperature Metastable Magnets

Rodolphe Clérac, Hitoshi Miyasaka, Masahiro Yamashita, and Claude Coulon

J. Am Chem. Soc., 2002, 124, 12837-12844.

Magnetic/Conducting Hybrid Compound Composed of 1-D Chain [MnII2Cl5(EtOH)]-∞ and BEDT-TTF Stacking Layer

Hitoshi Miyasaka, Yuko Yoshino, Tomohiko Ishii, Ryo Kanehama, Toshio Manabe, Masahiro Yamashita, Hiroyuki Nishikawa, and Isao Ikemoto

J. Solid State Chem., 2002, 168, 418-426.

Tuning of Spin Density Wave Strengths in Quasi-One-Dimensional Mixed-Halogen-Bridged Nickel(III) Complexes with Strong Electron Correlation, [NiIII(chxn)2Cl1-xBrx](NO3)2

Toshio Manabe, Kohei Yokoyama, Sachie Furukawa, Chihiro Kachi-Terajima, Kazuya Nakata, Fumiyasu Iwahori, Hitoshi Miyasaka, Ken-ichi Sugiura, Masahiro Yamashita, Hideo Kishida, and Hiroshi Okamoto

Inorg. Chem., 2002, 41, 4993-4995.

Reactions of Mn(III) Quadridentate Schiff Base Compounds with TCNQ Anion to Form Unusual TCNQ Derivatives by Alcoholysis

Hitoshi Miyasaka, Kunihisa Sugimoto, Ken-Ichi Sugiura, Tomohiko Ishii, and Masahiro Yamashita

Mol. Cryst. Liq. Cryst., 2002, 379, 197-204.

Out-of-plane Dimer Structures and Magnetic Properties of Mn(III) Quadridentate Schiff Base Compounds with N, N’-(1, 1, 2, 2-Tetramethylethylene)bis(5-chlorosalicylideneiminato)

Hitoshi Miyasaka, Kaori Mizushima, Sachie Frukawa, Tomohiko Ishii, Ken-Ichi Sugiura, and Masahiro Yamashita

Mol. Cryst. Liq. Cryst., 2002, 379, 171-178.

Synthesis, Structure and Magnetic Properties of the Antiferromagnetic Hexamanganese Cluster [Mn6(m4-O)2(O2CC6HF4)10(HO2CCH3)4]·(C7H8)

Kazuya Nakata, Hitoshi Miyasaka, Tomohiko Ishii, Masahiro Yamashita, and Kunio Awaga

Mol. Cryst. Liq. Cryst., 2002, 379, 211-216.

A Chemical Modification of a Mn12 Single-Molecule Magnet by Replacing Carboxylate Anions with Diphenylphosphate Anions

Takayoshi Kuroda-Sowa, Tomoji Fukuda, Shinsuke Miyoshi, Masahiko Maekawa, Megumu Munakata, Hitoshi Miyasaka, and Masahiro Yamashita

Chem. Lett., 2002, 7, 682-683.

Construction of a One-Dimensional Chain Composed of Mn6 Clusters and 4,4’-Bipyridine Linkers: The First Step for Creation of “Nano-Dots-Wires”

Kazuya Nakata, Hitoshi Miyasaka, Kunihisa Sugimoto, Tomohiko Ishii, Ken-ichi Sugiura, and Masahiro Yamashita

Chem. Lett., 2002, 7, 658-659.

Physical Properties of Quasi-One-Dimensional Mixed-Metal and Mixed-Halogen Complexes, Ni1-xPdx(chxn)2ClyBr1-yY2

Toshio Manabe, Kouhei Yokoyama, Tomohiko Ishii, Hitoshi Miyasaka, Hiroyuki Matsuzaka, Masahiro Yamashita, Takuya Kawashima, Hiruyuki Matsuzaki, Hideo Kishida, Hiroshi Okamoto, Kazuhiro Marumoto, Hisaaki Tanaka, Hiroshi Itoh, and Sin-ichi Kuroda

Mol. Cryst. Liq. Cryst., 2002, 376, 165-170.

Crystal and Electronic Structures of Quasi-One-Dimensional Halogen-Bridged Binuclear Platinum Complexes, {(CnH2n+1)2NH2}4[Pt2(pop)4I] (n = 2-6)

Kouichi Takizawa, Tomohiko Ishii, Hitoshi Miyasaka, Hiroyuki Matsuzaka, Masahiro Yamashita, Takuya Kawashima, Hiroyuki Matsuzaki, Hideo Kishida, and Hiroshi Okamoto

Mol. Cryst. Liq. Cryst., 2002, 376, 159-164.

Syntheses and Physical Properties of Complexes of Fullerene with Magnetic Metal Porphyrins

Naoko Aizawa, Hatsune Hara, Tomohiko Ishii, Masahiro Yamashita, Hitoshi Miyasaka, Hiroyuki Matsuzaka, Takeshi Kodama, Kouichi Kikuchi, and Isao Ikemoto

Mol. Cryst. Liq. Cryst., 2002, 376, 13-18.

Creations of Solitons and Polarons in MX-Chain Compounds, {[Pt(en)2][PtX2(en)2]}3(CuX4)4 (X = Cl and Br)

H. Aso, T. Manabe, T. Kawashima, T. Ishii, H. Miyasaka, H. Matsuzaka, M. Yamashita, Hassanuddin, N. Kuroda, and M. Shiro

Mol. Cryst. Liq. Cryst., 2002, 376, 7-12.

Structure and electrochemistry of the bridging-ligand mono-substituted diruthenium compound, [Ru2II,III(O2CCH3)3(admpym)(Cl)(MeOH)] (Hadmpym = 2-amino-4,6-dimethyl-pyrimidine)

Chihiro Kachi-Terajima, Hitoshi Miyasaka, Tomohiko Ishii, Ken-ichi Sugiura, and Masahiro Yamashita

Inorg. Chimi. Acta, 2002, 332, 210-215.

Tuning of Electronic Structures of Quasi-One-Dimensional Bromo-Bridged Ni(II) Complexes with Strong Electron-Correlation by Doping of Co(III) Ions, [Ni1-xCox(Chxn)2Br]Br2

M. Yamashita, K. Yokoyama, S. Frukawa, T. Manabe, T. Ono, K. Nakata, C. Kachi-Terajima, F. Iwahori, T. Ishii, H. Miyasaka, K. Sugiura, H. Matsuzaki, H. Kishida, H. Okamoto, H. Tanaka, Y. Hasegawa, K. Marumoto, H. Ito, and S. Kuroda

Inorg. Chem., 2002, 41, 1998-2000.

Electron spin resonance studies of Co(tbp)·C60 single crystal

H. Tanaka, K. Marumoto, S. Kuroda, T. Ishii, R. Kanehama, N. Aizawa, H. Matsuzaka, K. Sugiura, H. Miyasaka, T. Kodama, K. Kikuchi, I. Ikemoto, and M. Yamashita

J. Phys.: Condens. Matter., 2002, 14, 3993-4000.

Out-of-Plane Dimers of Mn(III) Quadridentate Schiff-Base Complexes with Saltmen2- and Naphtmen2- Ligands : Structure Analysis and Ferromagnetic Exchange

Hitoshi Miyasaka, Rodolphe Clérac, Tomohiko Ishii, Ho-Chol Chang, Susumu Kitagawa, and Masahiro Yamashita

J. Chem. Soc., Dalton Trans., 2002, 1528-1534.

Syntheses and Physical Prpperties of Quasi-One-Dimensional Halogen-Bridged CuII-PtIV Mixed-Metal Complexes [Cu(chxn)2][PtX2(chxn)2]X4

Takuya Kawashima, Kenzi Takai, Hidemitsu Aso, Toshio Manabe, Kouichi Takizawa, Chihiro Kachi-Terajima, Tomohiko Ishii, Hitoshi Miyasaka, Hiroyuki Matsuzaka, Masahiro Yamashita, Hiroshi Okamoto, Hiroshi Kitagawa, Motoo Shiro, and Koshiro Toriumi

Inorg. Chem., 2001, 40, 6651-6655.

Effects of Magnetic Anisotropy on Magnetization in Molecular Mesoscopic Magnet Fe8

Miki Ueda, Satoru Maegawa, Hitoshi Miyasaka, and Susumu Kitagawa

J. Phys. Soc. Jpn., 2001, 70, 3084-3088.

Fullerene C60 exhibiting a strong intermolecular interaction in a cocrystallite with C4 symmetrical cobalt tetrakis(di-tert-butylphenyl)porphyrine

Tomohiko Ishii, Ryo Kanehama, Naoko Aizawa, Masahiro Yamashita, Hiroyuki Matsuzaka, Ken-ichi Sugiura, Hitoshi Miyasaka, Takeshi Kodama, Kouichi Kikuchi, Isao Ikemoto, Hisaaki Tanaka, Kazuhiro Marumoto, and Shin-ichi Kuroda

J. Chem. Soc., Dalton Trans., 2001, 2975-2980.

A New Metal-Metal Bonded Diruthenium(II, III) Compound Bridged by the Dianionic Tridentate Ligand N-(2-Pyridyl)-2-Oxy-5-Chlorobenzylaminate (5-Clsalpy2-)

Hitoshi Miyasaka, Chihiro Kachi-Terajima, Tomohiko Ishii, and Masahiro Yamashita

J. Chem. Soc., Dalton Trans., 2001, 1929-1930.

Syntheses, Structures, and Physicochemical Properties of Diruthenium Compounds of Tetrachlorocatecholate with Metal-Metal Bonded Ru3+(m-OR)2Ru3+ and Ru3.5+(m-OR)2Ru3.5+ Cores (R = CH3 and C2H5)

Hitoshi Miyasaka, Ho-Chol Chang, Katsunori Mochizuki, and Susumu Kitagawa

Inorg. Chem., 2001, 40, 3544-3554.

The First X-ray Structure of a One-Dimensional Chain of Linked RuII=RuII Units

Hitoshi Miyasaka, Rodolphe Clérac, Cristian S. Campos-Fernández and Kim R. Dunbar,

J. Chem. Soc. Dalton Trans., 2001 858-861.

Metal-Metal Bonded Diruthenium(II, III) Assemblies with the Polycyano Anionic Linkers N(CN)2-, C(CN)3-, and 1,4-Dicyanamido-2,5-Dimethylbenzene (DM-Dicyd2-): Syntheses, Structures and Magnetic Properties

Hitoshi Miyasaka, Rodolphe Clérac, Cristian S. Campos-Fernández and Kim R. Dunbar

Inorg. Chem., 2001, 39, 1663-1671.

New Molecular Assemblies of Redox Isomers, [CrIII(X4SQ)3-n(X4Cat)n]-n (X = Cl and Br; n = 0, 1, and 2), with Metallocenium Cations, [MIIICp2]+ (M = Co and Fe): X-ray Crystal Structures and Physical Properties

Ho-Chol Chang, Hitoshi Miyasaka, and Susumu Kitagawa,

Inorg. Chem., 2001, 40, 146-156.

One-Dimensional Assemblies of Dirhodium Units Bridged by N,N’-Dicyanoquinonediimine Ligands

Hitoshi Miyasaka, Cristian S. Campos-Fernández, José Ramón Galán-Mascarós, and Kim R. Dunbar,

Inorg. Chem., 2000, 39, 5870-5873.

Hydrogen-Bonded Network of Dimeric Copper Complex of Vanillic Acid (HVA), [Cu(VA)2(H2O)]2

Zhu Longguan, Susumu Kitagawa, Ho-Chol Chang, and Hitoshi Miyasaka,

Mol. Cryst. Liq. Cryst., 2000, 342, 97-102.

Synthesis and Crystal Structure of New Salicylate-Bridged Coordination Polymer, [Cu2(ssal)2(pyz)(MeOH)2]n

Zhu Longguan, Susumu Kitagawa, Mitsuru Kondo, and Hitoshi Miyasaka,

Chem. Lett., 2000, 536-537.

Hexagonal Layered Materials Composed of [M2(O2CCF3)4] (M = Ru and Rh) Donors and TCNQ Acceptor

Hitoshi Miyasaka, Cristian S. Campos-Fernández, Rodolphe Clérac, and Kim R. Dunbar,

Angew. Chem. Int. Ed., 2000, 112, 3989-3993.

Ferrimagnetic Property of Two-Dimensional Layered Compound K[Mn(3-MeOsalen)]2[Cr(CN)6]·H2O

Hitoshi Miyasaka, Hisashi Okawa, and Naohide Matsumoto,

Mol. Cryst. Liq. Cryst., 1999, 335, 303-311.

[{Mn(salen)CN}n]: The First One-Dimensional Chain with Alternating High-Spin and Low-Spin MnIII Centers Exhibits Metamagnetism

Naohide Matsumoto, Yukinari Sunatsuki, Hitoshi Miyasaka, Yuzo Hashimoto, Dominique Luneau, and Jean-Pierre Tuchagues,

Angew. Chem. Int. Ed., 1999, 38, 171-173.

FeIIPbII and FeIII complexes of macrocyclic compartmental ligands: different cyclization in stepwise template synthesis using FeII/PbII or FeIII/PbII pairs

Hideki Furutachi, Akiko Ishida, Hitoshi Miyasaka, Nobuo Fukita, Masaaki Ohba, Hisashi Okawa, and Masayuki Koikawa,

J. Chem. Soc., Dalton Trans., 1999, 367-372.

An assembly compound [K(18-crown-6)(MeOH)2][Mn(5-Clsalen)(H2O)(MeOH)]2[Fe(CN)6]·4MeOH of isolated metal centers and coversion into a ferrimagnetic compound by desolvation [18-crown-6 = 1,4,7,10,13, 16-hexaoxacyclooctadecane, 5-Clsalen = N, N'-ethylenebis(5-chlorosalicylideneiminate)]

Hitoshi Miyasaka, Hisashi Okawa, Akira Miyazaki, and Toshiaki Enoki,

J. Chem. Soc., Dalton Trans., 1998, 3991-3996.

Synthesis, Crystal and Network Structures, and Magnetic Properties of a Hybrid Layered Compound: [K(18-cr)(2-PrOH)2][{Mn(acacen)}2{Fe(CN)6}] (18-cr = 18-Crown-6-ether, acacen = N, N'-Ethylenebis(acetylacetonylideneiminate))

Hitoshi Miyasaka, Hisashi Okawa, Akira Miyazaki, and Toshiaki Enoki,

Inorg. Chem., 1998, 37, 4878-4883.

The Synthesis and Characterization of Two-dimensional Ferromagnetic Extended Structures Containing High-Spin (S = 5/2) and Low-Spin (S = 1/2) Iron(III) Bridged by Cyanide Groups

Nazzareno Re, Raffaella Crescenzi, Carlo Floriani, Hitoshi Miyasaka, and Naohide Matsumoto,

Inorg. Chem., 1998, 37, 2717-2722.

Assembling Bi-, Tri- and Penta-nuclear Complexes into Extended Structures Using a Desolvation Reaction: Synthesis, Structure and Magnetic Properties of Manganese(III)-Schiff- Base-Hexacyanoferrate Polymeric Compounds and Their Derived Extended Structures

Hitoshi Miyasaka, Hidenori Ieda, Naohide Matsumoto, Nazzareno Re, Raffaella Crescenzi, and Carlo Floriani,

Inorg. Chem., 1998, 37, 255-263.

Dinuclear Complexes of MnII, CoII and ZnII Triply Bridged by Carboxylate Groups: Structures, Properties and Catalase-like Function

Masako Yamami, Megumi Tanaka, Hiroshi Sakiyama, Takeichiro Koga, Kensuke Kobayashi, Hitoshi Miyasaka, Masaaki Ohba, and Hisashi Okawa,

J. Chem. Soc., Dalton Trans., 1997, 4595-4602.

Proton-Dependent Monomer - Oligomer Interconversion of Metal Complexes

Naohide Matsumoto, Yukiko Mizuguchi, Genjin Mago, Shingo Eguchi, Hitoshi Miyasaka, Toshio Nakashima, and Jean-Pierre Tuchagues,

Angew. Chem. Int. Ed. Engl., 1997, 36, 1860-1862.

Steric-Hindrance Effect of a Substituent in the Self-Assembly Process of Copper(II) Complexes with Quadridentate Schiff-Base Ligands Involving a 2-Substituted-Imidazole Moiety

Naohide Matsumoto, Masaaki Mimura, Yukinari Sunatsuki, Shingo Eguchi, Yukiko Mizuguchi, Hitoshi Miyasaka, and Toshio Nakashima,

Bull. Chem. Soc. Jpn., 1997, 70, 2461-2472.

Copper(II) Complexes of N, N'-Bis(2-substituted-imidazol-4-ylmethylene)-3,3'-diaminodipropylamine (2-Substituent = H, Me): D and L Enantiomorphs of the Protonated Complex Formed by Hydrogen Bonds

Hitoshi Miyasaka, Shingo Okamura, Toshio Nakashima, and Naohide Matsumoto,

Inorg. Chem., 1997, 36, 4329-4335.

One-dimensinal Chain and Discrete Trinuclear Compounds Derived from Assembly Reaction of [Mn(saltmen)(H2O)]ClO4 and K2[Hg(CN)4] {saltmen = N, N'-(1, 1, 2, 2-tetramethylethylene)bis(salicylideneiminato) dianion}

Hitoshi Miyasaka and Naohide Matsumoto,

Chem. Lett., 1997, 5, 427-428.

One-dimensional Structures of Manganese(II) Complexes [MnII(hfac)2L] (hfac = Hexafluoroacetylacetonate Anion; L = N-(4-Pyridylmethyl)imidazole, Trans-1,2-bis(4-pyridyl)ethylene, Imidazole)

Genjin Mago, Miyuki Hinago, Hitoshi Miyasaka, Naohide Matsumoto, and Hisashi Okawa,

Inorg. Chimi. Acta, 1997, 254, 145-150.

Synthesis, Crystal Structure, and Magnetic Property of a Ferrimagnetic Layer Compound, [NEt4][Mn(5-Clsalen)]2[Fe(CN)6] (NEt4 = Tetraethylammonium, 5-Clsalen = N, N'-Ethylenebis(5-chlorosalicylideneiminato))

Hitoshi Miyasaka, Naohide Matsumoto, Nazzareno Re, Emma Gallo, and Carlo Floriani,

Inorg. Chem., 1997, 36, 670-676.

Magnetic Properties of a One-Dimensional Ferromagnet Containingt a Mn(III)-NC-Fe(III) Linkage: Synthesis and Crystal Structure of a Chainlike [Mn(acacen)Fe(CN)6]n2n-

Nazzareno Re, Emma Gallo, Carlo Floriani, Hitoshi Miyasaka, and Naohide Matsumoto,

Inorg. Chem., 1996, 35, 6004-6008.

Anomalous Magnetic Properties of [K{Mn(3-MeOsalen)}2{Mn(CN)6}]. A Metamagnet Exhibiting a Strong Negative Magnetization (3-MeOsalen = N, N'-Ethylenebis(3-methoxysalicylideneaminato)

Nazzareno Re, Emma Gallo, Carlo Floriani, Hitoshi Miyasaka, and Naohide Matsumoto,

Inorg. Chem., 1996, 35, 5964-5965.

Synthesis and Characterization of Alkoxo-oxygen-bridged Copper(II) Complexes having Disc- and Rod-like Shapes

Shingo Eguchi, Takeshi Nozaki, Hitoshi Miyasaka, Naohide Matsumoto, Hisashi Okawa, Susumu Kohata, and Naomi Hoshino-Miyajima,

J. Chem. Soc., Dalton Trans., 1996, 1761-1766.

Syntheses, Structures and Magnetic Properties of the Tricyanoethenolate Adducts of Quadridentate Schiff Base Manganese(III) Complexes

Yoshiki Sato, Hitoshi Miyasaka, Naohide Matsumoto, and Hisashi Okawa,

Inorg. Chimi. Acta, 1996, 247, 57-63.

Complexes Derived from the Reaction of Manganese(III) Schiff Base Complexes and Hexacyanoferrate(III): Syntheses, Multidimensional Network Structures, and Magnetic Properties

Hitoshi Miyasaka, Naohide Matsumoto, Hisashi Okawa, Nazzareno Re, Emma Gallo, and Carlo Floriani,

J. Am. Chem. Soc., 1996, 118, 981-994.

The Two-Dimensional Network Structure and Metamagnetic Properties of the 2 : 1 Complex of [Mn(3-MeOsalen)(H2O)]ClO4 and K3[Fe(CN)6]

Hitoshi Miyasaka, Naohide Matsumoto, Hisashi Okawa, Nazzareno Re, Emma Gallo, and Carlo Floriani,

Angew. Chem. Int. Ed. Engl., 1995, 34, 1446-1448.

The 1 : 2 and 1 : 4 p-p Type Molecular Adducts of Bis(N-alkyl-2-oxy-4-(1-naphthoyloxy)benzaldiminato)copper(II) and 1,3,5-Trinitrobenzene

Koji Nishijima, Takeshi Nozaki, Hitoshi Miyasaka, Genjin Mago, Naohide Matsumoto, and Hisashi Okawa,

Inorg. Chimi. Acta, 1995, 234, 131-137.

B-N Bond Formation by the Reaction of(N-(3-Methoxysalicylidene)-N'-(imidazol-4-ylmethylene)-1,3-propanediamino)copper(II) Perchlorate and Sodium Tetraphenylborate

Takeshi Nozaki, Naohide Matsumoto, Hisashi Okawa, Hitoshi Miyasaka, and Genjin Mago,

Inorg. Chem., 1995, 34, 2108-2112.

Photoreduction of Methylviologen Catalysed by Tri- or Tetra-Sulphophthalocyaninatozinc(II) in Aqueous Solutions

Kuninobu Kasuga, Hitoshi Miyasaka, Makoto Handa, and Masanori Dairaku,

Polyhedoron, 1995, 14, 1675-1679.

Preparation and Photocatalytic Properties of an Amphiphilic Phthalocyaninatosilicon(IV) Complex Having Methoxo Ligands at Its Axial Position

Kuninobu Kasuga, Hiroki Hayashi, Hitoshi Miyasaka, Makoto Handa, and Masanori Dairaku,

Polyhedoron, 1995, 14, 1393-1395.

ナノ空間材料ハンドブック　ナノ多孔性材料、ナノ層状物質等が切り開く新たな応用展開（有賀克彦監修）

第２章　金属錯体系（MOF類）　４節　酸化還元活性MOF　—選択的ガス吸着と物性制御—

高坂　亘、宮坂　等

エヌ・ティー・エス（NTS）, 2016, 164–175.

解説　分子パーツを組み上げて三次元磁性体を創る―新しい“ピラードレイヤー構造”というアプローチ

化学, 化学同人, 2015, 70 (5月号), 27-32.　表紙採用

CSJカレントレビュー16　スピン化学が拓く分子磁性の新展開: 設計から機能化まで（日本化学会編集）

フロントランナーに聞く（座談会）　分子磁性研究の新しい潮流の方向性

Chapter 11　金属錯体一次元磁性鎖：ナノワイヤーから相転移化合物まで

宮坂　等

化学同人, 2014, 2–11, 124–131.

配位空間の化学　—最新技術と応用—　Chemistry and Application of Coordination Space（北川　進監修）

第4章　磁性　5　低次元構造磁性：単一次元鎖磁石

宮坂　等

シーエムシー出版, 2009, 185-197.

超分子サイエンス＆テクノロジー　—基礎からイノベーションまでー（国武豊喜監修）

第3章　超分子の新しい展開とナノマテリアル　第1節　エマージング超分子—新しい超分子—　5　分子磁石

宮坂　等

エヌ・ティー・エス（NTS）, 2009, 501-511.

解説　導電性の単分子量子磁石—次世代量子磁気材料への期待

平賀広貴，宮坂　等，山下正廣

化学, 化学同人, 2008, 63, 12-17.

遷移金属錯体の固体物性化学（山下正廣　小島憲道編著）

２章　遷移金属錯体の磁気的性質　2-4　単一次元鎖磁石と単分子磁石ネットワーク

宮坂　等

三共出版, 2008, 121-151.

分子内電子移動を多次元格子に展開する–Taube理論を固体物性に活かすアプローチ

宮坂　等

化学と工業（特集　支部発　話題欄）日本化学会, 2008, 61-3 March, 226-227.

Hybridized Compounds Exhibiting Single-Molecule Magnet Behavior/Conductivity

Hiroki Hiraga, Hitoshi Miyasaka, Masahiro Yamashita

European White Book on Molecular Magnetism2, 2008 P189-191.

Magnetic Assemblies Based on Mn(III) Salen Analogues

Hitoshi Miyasaka, Ayumi Satoh, Satoshi Abe

Coord. Chem. Rev., 2007, 251, 2622-2664.

A look at molecular nanosized magnets from the aspect of inter-molecular interaction

Hitoshi Miyasaka and Masahiro Yamashita

Dalton Trans. (Frontiers), 2007, 399-406.

“Single-Chain Magnets”: Theoritical Approach and Experimental Systems

Claude Coulon, Hitoshi Miyasaka, Rodolphe Clérac

Structure and Bonding; Springer-Verlag Berlin Heidelberg, 2006, 122, 163-206 (Review).

化学フロンティア１６　チャンピオンレコードをもつ金属錯体最前線—新しい機能性錯体の構築に向けて（山下正廣・北川　進編）

一次元鎖の常識を破る：単一次元鎖磁石の開発とその理論解釈（21章）

宮坂　等

化学同人, 2006.

単分子量子磁石の分子間相互作用がおもしろい？—量子トンネル効果のチューニング

中田一弥、宮坂　等、山下正廣

化学, 2004, 59, 68-69.

集積型金属錯体の科学　物質機能の多様性を求めて（大川尚士・伊藤　翼編）

ナノワイヤー分子磁石（II部２章）

宮坂　等、山下正廣

化学同人, 2003.

一本の一次元金属錯体が磁石の性質を示す　ナノワイヤー単分子磁石ができたー室温単分子磁石を目指してー

宮坂　等、山下正廣

化学, 2002, 57, 12-16.

Cocrystallites Consisting of Metal Macrocycles with Fullerenes

Tomohiko Ishii, Naoko Aizawa, Ryo Kanehama, Masahiro Yamashita, Ken-ichi Sugiura, and Hitoshi Miyasaka

Coord. Chem. Rev., 2002, 226(1-2), 113-124.

Atomic Resolution of Porphyrines: Single-Molecule Observations of Porphyrinoid Compounds by Scanning Tunneling Microscopy

Ken-ichi Sugiura, Hitoshi Miyasaka, Tomohiko Ishii, and Masahiro Yamashita

Chemistry of Nanomolecular Systems – Towards the Realization of Nanomolecular Devices; T. Nakamura, T. Matsumoto, H. Tada, K. –I. Sugiura Eds., 2002, 59-72.